影像科学与光化学 ›› 1995, Vol. 13 ›› Issue (1): 61-67.DOI: 10.7517/j.issn.1674-0475.1995.01.61

• 研究论文 • 上一篇    下一篇

片状多层结构卤化银外延乳剂的光物理性质及感光性能的研究

卢涛, 徐永恩, 王素娥   

  1. 中国科学院感光化学研究所, 北京100101
  • 收稿日期:1994-03-29 修回日期:1994-09-24 出版日期:1995-02-20 发布日期:1995-02-20
  • 通讯作者: 王素娥
  • 基金资助:
    北京中关村地区联合分析测试中心的资助

THE PHOTOPHYSICAL AND PHOTOGRAPHIC PROPERTIES STUDY OF MULTISTRUCTURE EPITAXIAL TABULAR SILVER HALIDE MICROCRYSYALS

LU TAO, XU YONG-EN, WANG SU-E   

  1. The Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101, P.R. China
  • Received:1994-03-29 Revised:1994-09-24 Online:1995-02-20 Published:1995-02-20

摘要: 本文利用可控双注仪设计并制备了三种系列共二十种片状多层结构溴碘化银乳剂及其外延体。用X射线能谱仪(EDS)和电镜验证所设计的碘离子多层分布和氯化银外延体的位置,研究了它们的光物理性质和感光性能,发现外延AgCl对主体微晶性质的影响随层次结构和外延位置不同有很大的变化。若主体微晶结构合理,光电子利用效率已经较高,电子与空穴分离好,外延后其乳剂的感光度提高幅度反而不大。相反,若主体微晶的结构不合理,则外延可能导致两种结果:或增加潜影形成效率,提高感光度;或造成潜影分散,降低感光度。

关键词: 片状多层结构微晶, 卤化银外延乳剂, Dember效应

Abstract: A series of unepitaxial and epitaxial multistructure tabular silver halide microcrystals with the same content but different distribution of iodide ions were prepared by double-jet precipitation. The ditribution of iodide ions and the position of epitaxial AgCl in the micro-areas of a single microcrystal were analysed by the means of Scanning Transmissive Electron Microscope(STEM)and X-ray Energy Dispersive Spectrorneter(EDS).It was found that the iodide and chlorine ions are distributed in the different microareas of tabular microcrystals as designed.The photophysical and photographic properties were investigatd,The results showed that the influence of epitaxial AgCl on the property of tabular silver halide microcrystals apparently depends on the multistructure of original tabular iedobromide micrcocrystals. Reasonable structure with high utilizing efficiency of photoelectrons as well as with high original sensitivity has few contribution to enhancing its sensitivity after being epitaxized.On the other hand,there will cause two results after epitaxizing on the emulsion with unreasonable structure:increasing the efficiency of formation of latent image and increasing the dispersion of latent image.

Key words: multistructure tabular silver halide microcrystal, Dember effect, epitaxial emulsion