卤化银乳剂制备中的新型掺杂剂

doi:10.7517/j.issn.1674-0475.2001.01.72

影像科学与光化学 ›› 2001, Vol. 19 ›› Issue (1): 72-78.DOI: 10.7517/j.issn.1674-0475.2001.01.72

• 应用与发展 • 上一篇

卤化银乳剂制备中的新型掺杂剂

戴晖, 梁冰, 庄思永

华东理工大学精细化工研究所, 上海 200237

收稿日期:2000-06-19 修回日期:2000-09-15 出版日期:2001-02-20 发布日期:2001-02-20
通讯作者: 庄思永
基金资助:
国家自然科学基金资助项目(20073013)

NEW TYPES OF DOPANTS IN SILVER HALIDE EMULSIONS

DAI Hui, LIANG Bing, ZHUANG Si-yong

Research Institute of Fine Chemical, East China University of Science and Technology, Shanghai 200237, P.R.China

Received:2000-06-19 Revised:2000-09-15 Online:2001-02-20 Published:2001-02-20

摘要/Abstract

摘要： 本文综述了近年来乳剂制备中常用的新型掺杂剂,较详细地介绍了两种能提高光电子利用效率的掺杂剂,即过渡金属络合物浅电子陷阱掺杂剂和羧酸盐(酯)有机空穴陷阱掺杂剂,总结了掺杂剂的选择原则,并举例说明了掺杂剂对乳剂感光度的影响.

关键词: 浅电子陷阱掺杂剂, 空穴陷阱掺杂剂, 过渡金属络合物, 羧酸盐(酯)

Abstract: Two new types of dopants are introduced in this paper. One type is a transition metal complex dopant which can create shallow electron traps in silver halide grains. The other is a carboxylate organic compound which can create hole traps in the silver halide grains. Both types of traps can effectively prevent the photoelectrons and the holes from recombination and hence increase the efficiency of the latent image formation, resulting in significant increase of the sensitivity of the photographic emulsions. The principles of selecting dopants are presented. Some experimental results in patents are provided to illustrate the effects of dopants on the photographic properties of the silver halide emulsion.

Key words: dopant, shallow electron traps, hole traps, transition metal complex

中图分类号:

TQ57

戴晖, 梁冰, 庄思永. 卤化银乳剂制备中的新型掺杂剂[J]. 影像科学与光化学, 2001, 19(1): 72-78.

DAI Hui, LIANG Bing, ZHUANG Si-yong . NEW TYPES OF DOPANTS IN SILVER HALIDE EMULSIONS[J]. Imaging Science and Photochemistry, 2001, 19(1): 72-78.

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卤化银乳剂制备中的新型掺杂剂

NEW TYPES OF DOPANTS IN SILVER HALIDE EMULSIONS

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