菁染料和份菁染料薄膜的光稳定性研究

doi:10.7517/j.issn.1674-0475.2002.01.10

影像科学与光化学 ›› 2002, Vol. 20 ›› Issue (1): 10-18.DOI: 10.7517/j.issn.1674-0475.2002.01.10

菁染料和份菁染料薄膜的光稳定性研究

杨松杰¹, 孟凡顺¹, 田禾¹, 贡雪东², 肖鹤鸣²

1. 华东理工大学, 精细化工研究所, 上海, 200237;
2. 南京理工大学, 化学系, 南京, 210094

收稿日期:2001-03-26 修回日期:2001-05-09 出版日期:2002-01-23 发布日期:2002-01-23
通讯作者: 田禾
基金资助:
国家自然科学基金资助项目(29836150)

THE PHOTOSTABILITY OF CYANINE DYES AND MEROCYANINE DYES IN THIN FILMS

YANG Song-jie¹, MENG Fan-shun¹, TIAN He¹, GONG Xue-dong², XIAO He-ming²

1. Institute of Fine Chemicals, East China University of Science &, Technology, Shanghai 200237, P. R. China;
2. Department of Chemistry , Nanjing University of Science & Technology, Nanjing 210094, P. R. China

Received:2001-03-26 Revised:2001-05-09 Online:2002-01-23 Published:2002-01-23

摘要/Abstract

摘要： 利用UV-Vis吸收光谱仪和光化学反应器研究了菁染料和份菁染料薄膜的光降解动力学.与相应的份菁染料相比,携带正电荷的菁染料薄膜具有相对较好的光稳定性.运用量子化学中的SCF-MO-PM3方法,全优化计算了这些染料的分子几何构型和电子结构,并解释了染料的光稳定性与其分子结构的关系.

关键词: 菁染料, 光稳定性, 份菁染料, 量子化学计算

Abstract: The photodegradation kinetics of cyanine dyes and merocyanine dyes in thin films has been studied by UV-Vis absorption spectroscopy.Those cyanine dyes holding a positive charge in thin films have relative good photostability comparing with merocyanines in thin films.The relationship between photostability and chemical structure of dyes has been elucidated by SCF-MO-PM3 calculations.

Key words: cyanine dyes, photostability, merocyanine dyes, SCF-MO-PM3 calculations

中图分类号:

杨松杰, 孟凡顺, 田禾, 贡雪东, 肖鹤鸣. 菁染料和份菁染料薄膜的光稳定性研究[J]. 影像科学与光化学, 2002, 20(1): 10-18.

YANG Song-jie, MENG Fan-shun, TIAN He, GONG Xue-dong, XIAO He-ming. THE PHOTOSTABILITY OF CYANINE DYES AND MEROCYANINE DYES IN THIN FILMS[J]. Imaging Science and Photochemistry, 2002, 20(1): 10-18.

参考文献

[1] 米斯C E K,詹姆斯T H.照相过程理论[M].北京:科学出版社,1979.249-320.Mees C E K,James T H.The Theory of the Photographic Process[M].Beijing:Science Press,1979.249-320.
[2] 干福熹.数字光盘存储技术[M].北京:科学出版社,1998.165-167.Gan F X.Digital Optical Disks Storage Technology[M].Beijing:Science Press,1998.165-167.
[3] Shealay D B,Lohrmann R,et al.Spectral characterization and evaluation of modified near-infrared laser dyes for DNA sequencing[J].Applied Spectroscopy,1995,49:1815-1820.
[4] Li J,Chen P,et al.Study on the photofading of near-infrared absorbing indolenine cyanine dyes[J].Chinese Chemical Letters,1996,7(12):1121-1124.
[5] Chibisov A K,Zakharova G V,et al.Effects of substituents in the polymethine chain on the photoprocesses in indodicarbocyanine dyes[J].J.Chem.Soc.,Faraday Trans.,1996,92(24);4917-4925.
[6] Kopaindky B,Qiu P,et al.Lifetime,photostability and chemical structure of IR heptamethine cyanine dyes absorbing beyond 1 μm[J].Appl.Phys.,1982,B29:15-18.
[7] 李军,陈萍,赵江,等.近红外吸收菁染料光氧化反应机理的研究[J].感光科学与光化学,1996,14(4):314-319.Li J,Chen P,Zhao J,et al.Study on the mechanism of photooxidation of near-infrared absorbing cyanine dyes[J].Photographic Science and Photochemistry,1996,14(4):314-319.
[8] Zaitsev A,Yang X.Penetrated ion pairs:photochemistry of cyanine dyes within organic borates[J].J.Am.Chem.Soc.,1992,114:793-794.
[9] Tatikolov A S,Dzhulibekov Kh S,et al.Influence of "inert" counterions on the photochemistry of some cationic polymethine dyes[J].J.Phys.Chem.,1995,99:6525-6529.
[10] 杨松杰,孟凡顺,陈孔常,等.菁染料和份菁染料的合成及其溶液的光稳定性研究[J].感光科学与光化学,2001,19(3):185.Yang S J,Meng F S,Chen K C,et al.Synthesis and photostability of cyanine and merocyanine dyes solution[J].Photographic Science and Photochemistry,2001,19(3):185.
[11] Griffiths J,Hawkins C.Oxidation by singlet oxygen of arylazonaphthols exhibiting azohydrazone tautomerism[J].J.Chem.Soc.,Perkin Ⅱ,1977,747-752.
[12] Spada L T,Foote C S.Electron-transfer photooxidation.3.Detection of radical-ion intermediates in the cyanoaromaticsensitized photooxidation of trans-and cis-stilbene[J].J.Am.Chem.Soc.,1980,102:391-393.
[13] Dyumaev K M,Manenkov A A,et al.Dyes in modified polymers:problems of photostability and conversion efficiency at high intensities[J].J.Opt.Soc.Am.,1992,B9:143-151.
[14] Rettig W,Strehmel B,Schrader S,et al.Applied Fluorescence in Chemistry,Biology and Medicine[M].Berlin:Springer,1999.193-240.
[15] Costela A,Florido F,et al.Solid-state dye lasers based on copolymers of 2-hydroxyethyl methacrylate and methyl methacrylate doped with rhodamine 6G[J].Appl.Phys.,1995,B60:383-389.
[16] Stewart J J P.Optimization of parameters for semiempirical methods I.Method[J].J.Comput.Chem.,1989,10:209-220.

菁染料和份菁染料薄膜的光稳定性研究

THE PHOTOSTABILITY OF CYANINE DYES AND MEROCYANINE DYES IN THIN FILMS

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	马亚光, 张玉涛, 马一宇, 郭志前, 朱为宏. 基于菁染料高选择性检测半胱氨酸的近红外荧光探针[J]. 影像科学与光化学, 2018, 36(3): 236-244.
[2]	俞丹萍, 刘亚伟, 申亮, 李富友. 花菁染料负载的聚合物纳米材料用于次氯酸可视化检测的研究[J]. 影像科学与光化学, 2017, 35(3): 290-296.
[3]	李姝静, 周自若, 岳军治, 周威, 王心蕊, 白冬生. 虎杖甙/HP-β-CD包合物的制备及光稳定性研究[J]. 影像科学与光化学, 2015, 33(6): 487-493.
[4]	陈秀英, 郭琳, 贾显林, 高海燕, 郑昌戈. 新型中位取代七甲川菁染料的合成及光稳定性研究[J]. 影像科学与光化学, 2012, (5): 375-383.
[5]	谢普会, 郭丰启, 李娟, 何勇. 新型芳香重氮盐的光与热稳定性研究[J]. 影像科学与光化学, 2012, 30(2): 118-123.
[6]	陈秀英, 赵小琴, 郑昌戈. 新型不对称五甲川菁染料的合成及光稳定性能研究[J]. 影像科学与光化学, 2008, 26(4): 291-298.
[7]	杨少鹏, 李春雷, 范闪闪, 李晓苇, 傅广生. 阴阳离子菁染料超快荧光动力学特性研究[J]. 影像科学与光化学, 2007, 25(5): 364-373.
[8]	张志颖, 刘春艳. 反胶束体系中水团的笼效应[J]. 影像科学与光化学, 2006, 24(1): 1-8.
[9]	孙承华, 段培成, 周树云, 陈萍. 短波长菁染料对氯化银乳剂的光谱增感作用[J]. 影像科学与光化学, 2003, 21(3): 184-189.
[10]	赵红莉, 袁慧慧, 蓝闽波. 菁染料在荧光探针及光动力疗法中的应用[J]. 影像科学与光化学, 2003, 21(3): 212-222.
[11]	张俊平, 周树云, 陈萍, 速水正明, 冈崎庸树. 混合溶剂对可录型光盘中吲哚类菁染料薄膜性能的影响[J]. 影像科学与光化学, 2003, 21(2): 81-88.
[12]	闫文璠, 钱惠红, 黄德音. 咪碳菁类染料在溶液中的聚集行为[J]. 影像科学与光化学, 2003, 21(1): 25-29.
[13]	孟刚, 邹小兵, 郑泽根, 陈丽娟, 彭必先. 铁炭微电解-亚铁还原氧化法处理花菁废水的研究[J]. 影像科学与光化学, 2002, 20(4): 303-312.
[14]	杨松杰, 何元君, 田禾. 新型双发色团固体激光染料薄膜的光稳定性研究[J]. 影像科学与光化学, 2002, 20(1): 1-9.
[15]	杨松杰, 王朝晖, 陈孔常, 田禾. 含二茂铁基偶氮染料的光稳定性研究[J]. 影像科学与光化学, 2002, 20(1): 33-38.