脲基苯乙炔4-’(对甲基苯基)-6-苯基-2,2’-二联吡啶铂(Ⅱ)络合物的合成

doi:10.7517/j.issn.1674-0475.2006.02.81

影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (2): 81-86.DOI: 10.7517/j.issn.1674-0475.2006.02.81

• 研究快讯 • 下一篇

脲基苯乙炔4-’(对甲基苯基)-6-苯基-2,2’-二联吡啶铂(Ⅱ)络合物的合成

潘敦^1,2, 吴骊珠¹, 武小玲^1,2, 张丽萍¹, 佟振合¹

1. 中国科学院, 理化技术研究所, 北京, 100101;
2. 中国科学院, 研究生院, 北京, 100039

收稿日期:2006-01-04 修回日期:2006-01-25 出版日期:2006-03-23 发布日期:2006-03-23
通讯作者: 吴骊珠,佟振合E-mail:lzwu@mail.ipc.ac.cn;cht ung@mail.ipc.ac.cn.
基金资助:
国家自然科学基金(20125207,20333080,20332040,50473048,20403025);国家重点基础研究发展规划项目(973)(2003CB716802,2004CB719903);中国科学院知识创新工程项目(KJCX2-SW-H15)

Synthesis and Photophysical Studies of Platinum(Ⅱ) Polypyridine Complexes by Ancillary Urea Acetylide Ligand

PAN Dun^1,2, WU Li-zhu¹, WU Xiao-ling^1,2, ZHANG Li-ping¹, TUNG Chen-ho(TONG Zhen-he)¹

1. Technical Insititute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China;
2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, P. R. China

Received:2006-01-04 Revised:2006-01-25 Online:2006-03-23 Published:2006-03-23

摘要/Abstract

摘要： 本文通过异氰酸酰化反应合成了含有脲基的苯乙炔新型配体及以它作为辅助配体的4’-(对甲基苯基)-6-苯基-2,2’-二联吡啶铂(Ⅱ)络合物,初步研究了铂(Ⅱ)络合物的光物理性质,发现由于脲基的存在,当浓度大于3.32×10^-5mol/L时铂(Ⅱ)络合物能够发生分子间簇集.

关键词: 多吡啶铂(Ⅱ)络合物, 脲基苯乙炔辅助配体, 簇集

Abstract: 4’-tolyl-cyclometalated platinum(Ⅱ) complex with urea acetylide as an ancillary ligand(P2) has been synthesized,and its photophysical properties have been investigated.It is noted that P2 tends to aggregate under relative low concentration in nonpolar solvent.

Key words: platinum(Ⅱ) polypyridine complexes, ancillary urea acetylide ligand, aggregation

中图分类号:

潘敦, 吴骊珠, 武小玲, 张丽萍, 佟振合. 脲基苯乙炔4-’(对甲基苯基)-6-苯基-2,2’-二联吡啶铂(Ⅱ)络合物的合成[J]. 影像科学与光化学, 2006, 24(2): 81-86.

PAN Dun, WU Li-zhu, WU Xiao-ling, ZHANG Li-ping, TUNG Chen-ho(TONG Zhen-he). Synthesis and Photophysical Studies of Platinum(Ⅱ) Polypyridine Complexes by Ancillary Urea Acetylide Ligand[J]. Imaging Science and Photochemistry, 2006, 24(2): 81-86.

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脲基苯乙炔4-’(对甲基苯基)-6-苯基-2,2’-二联吡啶铂(Ⅱ)络合物的合成

Synthesis and Photophysical Studies of Platinum(Ⅱ) Polypyridine Complexes by Ancillary Urea Acetylide Ligand

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