4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(Ⅱ)络合物的合成及光物理性质

doi:10.7517/j.issn.1674-0475.2006.03.161

影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (3): 161-166.DOI: 10.7517/j.issn.1674-0475.2006.03.161

• 研究快讯 • 下一篇

4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(Ⅱ)络合物的合成及光物理性质

韩雪, 吴骊珠, 吴梓新, 张丽萍, 佟振合

中国科学院, 理化技术研究所, 北京, 100080

收稿日期:2006-01-05 修回日期:2006-03-21 出版日期:2006-05-23 发布日期:2006-05-23
通讯作者: 吴骊珠,E-mail:lzwu@mail.ipc.ac.cn;佟振合,E-mail:chtung@mail.ipc.ac.cn.
基金资助:
科技部国家重点基础研究发展规划项目(2003CB716802,2004CB719903);国家自然科学基金资助项目(20125207,20333080,20332040);中科院基础局资助项目(KJCX2-SW-H15)

The Synthesis and Photophysical Properties of 4-(4-Tolyl-6-Phenyl-2,2′-Bipyridyl) Platinum(Ⅱ) Aryl-Substituted Acetylide Complexes

HAN Xue, WU Li-zhu, WU Zi-xin, ZHANG Li-ping, TONG Zhen-he(TUNG Chen-ho)

Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China

Received:2006-01-05 Revised:2006-03-21 Online:2006-05-23 Published:2006-05-23

摘要/Abstract

摘要： 设计合成以4-甲基苯基-6-苯基-2,2′-二联吡啶为主配体、芳炔为辅助配体的铂(Ⅱ)络合物1-3.与苯乙炔、萘乙炔为辅助配体的络合物1,2相比,蒽乙炔4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶铂(Ⅱ)络合物MLCT激发态的能量升高.

关键词: 多吡啶铂(Ⅱ)络合物, 芳炔, MLCT激发态

Abstract: 4-(4-tolyl)-6-phenyl-2,2′-bipyridylplatinum (Ⅱ) aryl-substituted acetylide complexes 1-3 were designed and synthesized.In contrast to complexes 1 and 2,when 9-acetylide-anthracene is employed as ancillary ligand,the energy of lowest emissive excited state of complex 3 increases.

Key words: polypyridyl platinum complexes, arylacetylene, MLCT excited state

中图分类号:

韩雪, 吴骊珠, 吴梓新, 张丽萍, 佟振合. 4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(Ⅱ)络合物的合成及光物理性质[J]. 影像科学与光化学, 2006, 24(3): 161-166.

HAN Xue, WU Li-zhu, WU Zi-xin, ZHANG Li-ping, TONG Zhen-he(TUNG Chen-ho). The Synthesis and Photophysical Properties of 4-(4-Tolyl-6-Phenyl-2,2′-Bipyridyl) Platinum(Ⅱ) Aryl-Substituted Acetylide Complexes[J]. Imaging Science and Photochemistry, 2006, 24(3): 161-166.

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4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(Ⅱ)络合物的合成及光物理性质

The Synthesis and Photophysical Properties of 4-(4-Tolyl-6-Phenyl-2,2′-Bipyridyl) Platinum(Ⅱ) Aryl-Substituted Acetylide Complexes

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