Gd3Al5O12:Eu3+柠檬酸盐硝酸盐燃烧法合成及其发光性能研究

doi:10.7517/j.issn.1674-0475.2006.03.225

影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (3): 225-230.DOI: 10.7517/j.issn.1674-0475.2006.03.225

Gd₃Al₅O₁₂:Eu³⁺柠檬酸盐硝酸盐燃烧法合成及其发光性能研究

罗岚¹, 刘庆峰², 刘茜², 陈燕波¹

1. 南昌大学, 材料科学与工程学院, 江西, 南昌, 330047;
2. 中国科学院, 上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室, 上海, 200050

收稿日期:2005-12-03 修回日期:2006-01-04 出版日期:2006-05-23 发布日期:2006-05-23
通讯作者: 罗岚,E-mail:luolan1190@sina.com.cn,luolan1190@163.com.
基金资助:
2005年南昌大学科学基金项目(Z02901);2005年江西省教育厅基金项目(Z02810);自然科学基金委主任基金资助项目(20151003/B01);上海市科学技术发展基金资助项目(纳米科技专项)(0259nm021)

Synthesis and Luminescent Properties of Gd₃Al₅O₁₂:Eu³⁺ by Nitric-Citric Combustion Process

LUO Lan¹, LIU Qing-feng², LIU Qian², CHEN Yan-bo¹

1. School of Material Science and Engineering, Nanchang University, Nanchang 330047, Jiangxi, P. R. China;
2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received:2005-12-03 Revised:2006-01-04 Online:2006-05-23 Published:2006-05-23

摘要/Abstract

摘要： 采用柠檬酸盐硝酸盐燃烧法,在较低的温度(900℃)下成功地合成单一晶相Gd₃Al₅O₁₂:Eu³⁺发光粉体,紫外激发荧光光谱分析表明,粉体615 nm和593 nm荧光发射源于Eu³⁺的⁵D₀-⁷F₂和⁵D₀-⁷F₁跃迁.该方法中各工艺条件(如pH值、柠檬酸/金属离子比、煅烧温度)对Gd₃Al₅O₁₂:Eu³⁺发光性能均有影响,通过试验得出了获得最佳发光性能荧光粉体的工艺参数.

关键词: 石榴石型铝酸钆, 铕, 柠檬酸盐硝酸盐燃烧合成法, 发光

Abstract: Pure Gd₃Al₅O₁₂:Eu³⁺ crystalline phase was formed at 900℃ with the precursor prepared by nitric-citric combustion.The luminescent properties of Gd₃Al₅O₁₂:Eu³⁺ was also described,and the emission of Gd₃Al₅O₁₂:Eu³⁺ at 615 nm and 593 nm was considered to be the Eu³⁺ ⁵D₀-⁷F₂ and Eu³⁺ ⁵D₀-⁷F₂ transition.The Synthesis process was reported in details,related to the pH value,citric acid/metal ion and calcinations temperature.

Key words: gadolinium-aluminum garnet, europium, citrate-nitrate combustion, luminescence

中图分类号:

TB332

罗岚, 刘庆峰, 刘茜, 陈燕波. Gd₃Al₅O₁₂:Eu³⁺柠檬酸盐硝酸盐燃烧法合成及其发光性能研究[J]. 影像科学与光化学, 2006, 24(3): 225-230.

LUO Lan, LIU Qing-feng, LIU Qian, CHEN Yan-bo. Synthesis and Luminescent Properties of Gd₃Al₅O₁₂:Eu³⁺ by Nitric-Citric Combustion Process[J]. Imaging Science and Photochemistry, 2006, 24(3): 225-230.

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Gd₃Al₅O₁₂:Eu³⁺柠檬酸盐硝酸盐燃烧法合成及其发光性能研究

Synthesis and Luminescent Properties of Gd₃Al₅O₁₂:Eu³⁺ by Nitric-Citric Combustion Process

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