光催化“全”分解水制H2与牺牲体系产H2的关系

doi:10.7517/j.issn.1674-0475.2009.04.314

影像科学与光化学 ›› 2009, Vol. 27 ›› Issue (4): 314-320.DOI: 10.7517/j.issn.1674-0475.2009.04.314

• 综述 • 上一篇

光催化“全”分解水制H₂与牺牲体系产H₂的关系

金振声

1. 河南大学特种功能材料重点实验室, 河南开封475004;
2. 中国科学院兰州化学物理研究所, 甘肃兰州730000

收稿日期:2008-12-24 修回日期:2009-04-21 出版日期:2009-07-23 发布日期:2009-07-23

Relationship Between Over-all Photosplitting of Water and Hydrogen Production from Photocatalytic System in the Presence of Sacrificial Agent

JIN Zhen-sheng

1. Key Laboratory of Special Functional Materials, Henan University, Kaifeng 475004, Henan, P. R. China;
2. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, P. R. China

Received:2008-12-24 Revised:2009-04-21 Online:2009-07-23 Published:2009-07-23

摘要/Abstract

摘要： 多相光催化“全”分解水制H₂的研究已走过约40年路程,至今未获得真正的突破,目前国内、外发表的许多可见光催化牺牲体系放H₂的文章,虽然它在氢离子还原机理方面有一定的参考意义,但它不能解决光催化“全”分解水制H₂问题,本文提醒我国光催化界:勿把可见光牺牲体系产H₂研究的结果,当成我们在分解水制H,方面取得的进展,应认真总结过去失败的经验教训,兼顾热力学和动力学两方面的要求,制订出正确的"全"分解水制H₂催化剂的研究策略。

关键词: 光催化, “全”分解水制H₂, 牺牲剂, 氢离子还原

Abstract: Although the study on the over-all photosplitting of water into H₂ and O₂ can be traced backed to ca.40 years ago,a real breakthrough has not been achieved in this field so far.Currently available published studies of H₂ evolution based on sacrificial systems by visible light at home and abroad may be meaningful in helping understand the reduction mechanism of hydrogen ion,but they are inapplicable to solving the problems emerging in over-all photosplitting of water.Thus the domestic academic circles involved in photocatalysis are reminded not to acknowledge that the achievements made in the researches of H₂ evolution via sacrificial systems as the progresses in the field of over-all photosplitting of water.It is suggested to summarize the unsuccessful practices in the past by taking into account both thermodynamic and kinetic requirements so as to establish a correct strategy for the study of the catalysts applicable to the over-all photosplitting of water.

Key words: photocatalysis, hydrogen production from over-all splitting of water, sacrificial agent, hydrogen ion reduction

中图分类号:

金振声. 光催化“全”分解水制H₂与牺牲体系产H₂的关系[J]. 影像科学与光化学, 2009, 27(4): 314-320.

JIN Zhen-sheng. Relationship Between Over-all Photosplitting of Water and Hydrogen Production from Photocatalytic System in the Presence of Sacrificial Agent[J]. Imaging Science and Photochemistry, 2009, 27(4): 314-320.

参考文献

[1] Frank E.Osterloh.Inorganic materials as catalysts for photochenfical splitting of water[J].Chem.Mater.,2008,20(1),35-54.
[2] 马刚峰,李越湘,吕功煊.等.氧硫锌固溶体可见光制氢性能研究[C].2008年全国太阳能光化学与光催化学术会议摘要.上海,2008,MC301-MC335.Ma G F,Li Y X,Lu G X,et al.Investigation of hydrogen production on visible-light-irradiated ZnOxS1-x[C].Abstract of 2008 National Conference on Solar Energy Photochemistry and Photocatalysis,Shanghai,MC301-MC335.
[3] 金振声,李庆霖.微多相光催化的进展[J].感光科学与光化学(影像科学与光化学),1987,5(2):49-57.Jin Z S,Li Q L,Progress in mlcro-heterogeneous photocatalysis[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),1987,5(2):49-57.
[4] Jin Z S,Li Q L,Zheng X H,et al.Surface properties of Pt-CdS andmechanism of photocatalytic dehydrogenation of aqueous alcohol[J].J.Photochem.Photobiol.A:Chem.,1993,71(1):85-96.
[5] Jin Z S,Feng L B,Li Q L,et al,Investigation of the relationship between molecular structure of aliphatic alcohols and their behaviorin photocatalytie dehydrogenationon Pt/CAS[J].J.Molec.Catal.,1991,70(3):351-361.
[6] Bao N Z,Shen L M,Tsuyoshi Takata,Kazunafi Domen.Self-ternplated synthesis of nanoporous CAS nanostructures for highly efficient photocatalytic hydrogen production under visible light[J].Chem.Mater.,2008,20(1):110-117.
[7] Abe T,Suzuki E,Nagoshi K,et al.Electron source in photoinduced hydrogen production on Pt-supported TiO₂ particles[J].J.Phys.Chem.B,1999,103(7):1119-1123.
[8] Kawai T,Sakata T.Conversion of carbohydrate into hydrDgen fuel by a photocatalytie process[J].Nature,1980,286:474-476.
[9] Ma W H,Zhao J C.Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytie system of dye-sensitized TiO₂ andTEMPO[J].Angew.Chem.Int.Ed.,2008,47(50):9730-9733.
[10] Fujishima A,Honda K.Electrochemical phomlysis of water at a semiconductor electrode[J].Nature,1972,238:37-38.
[11] Kiwi J,Gratzel M.Hydrogen evolution from water induced by visible light mediated by redox catalysis[J].Nature,1979,281:657-658.
[12] Wagner F T,Somorjai G A.Photocatalytie hydrogen production from water on Pt-free SrTiO₃ in alkali hydroxide solution[J].Nature,1980,285:559-560.
[13] Zou Z,Ye J,Sayama K,et al,Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst[J].Nature,2001,414:625-627.
[14] Lu D,luoue Y,Domes K,et al.Photocatalyst releasing hydrogen from water[J].Nature,2006,440:295.
[15] Calvin M.Solar energy by photosynthesis[J].Science,1974,184:375-381.
[16] Calvin M.Solar energy by photosynthesis:Manganese complex photolysis[J].Science,1974,185:376.
[17] Khaselev O,Turner J A.A monolithic photovoltaie-phtoelectrochemical devices for hydrogen production via water splitting[J].Scqence,1998,280:425-432.
[18] Khan S U M,Al-Shahry M,Ingler W B Jr.Efficient photochemical water splitting by a chemically modified n-TiO₂[J].Science,2002,297:2243-2245.
[19] Calvin M.Synthetic chloroplasts[J].Energy Research,1979,3(1):73-87.
[20] Porter G.Fuel from water[J].Proc.R.Inst.G.B.,1983,55(1):133-147.
[21] Lehn J M,Sauvage J P,Ziessel R.Photochemical water splitting continuous generation hydrngen and oxygen by irradiation of aqueous suspension of metal loaded strontiumtitanate[J].Nouv.J.Chim.,1980,4(11):623-627.
[22] Gai Y Q,Li J B,Lis S,et al.Apassivated codoping approachfor enhanced photoelectrochernieal activity[J].Phys.Rev.Lett.,2009,036402-1 to 036402-4.
[23] 石庆平,王闻声,吴鸣,等.光催化R&D的文献计量分布[C].98'全国光催化学术会议(NCP-98)会议论文摘要集,大连,1998,7-10.Shi Q P,Wang W S,Wu M,et al.Metrologic analysis on literature of photocatalysis[C].Abstract of 1998 National Conference on Photocatalysis,DaiJan,7-10.
[24] 葛堵根编著.光合作用--光子、激子、电子、质子、离子与光合膜之间的相互作用[M].合肥:安徽教育出版社,1991.1-7.Ke Bacon.Photosynthesis-Photons,Eexitons,Electrons,Protons,Ions,and Their Interactions with Photosynthetic Membrane[M].Hefei:Anhui Edueation Press,1991.1-7.

光催化“全”分解水制H₂与牺牲体系产H₂的关系

Relationship Between Over-all Photosplitting of Water and Hydrogen Production from Photocatalytic System in the Presence of Sacrificial Agent

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