Imaging Science and Photochemistry ›› 1987, Vol. 5 ›› Issue (2): 58-60.DOI: 10.7517/j.issn.1674-0475.1987.02.58

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THE ROLE OF SOME ORGANIC COMPOUNDS IN THE RECRYSTALLIZATION OF AQUEOUS AgBr DISPERSIONS

WANG RONG-QIN   

  1. Institute of Photographic Chemistry, Academia Sinica, Beijing
  • Received:1986-04-18 Revised:1986-11-28 Online:1987-05-20 Published:1987-05-20

Abstract: Turbidimetry was used at 21℃ to measure the growth rate of AgBr crystals which were dispersed in the aqueous solution of sodium dodecyls sulphate (SDS), 3,4-dimethyl-1,2,4-triazo-le-5-thione (DMT) or cetyl trimethyl ammonium bromide (CTAB) at pBr4 or pAg4. The results indicated that the increase of the average crystal volume was not due to the coagulation of particles but involved in a process of recrystallization, i.e. Ostwald ripening. The addition of SDS (10-5 mol·dm-3) causes the acceleration of AgBr recrystallization in pAg4 and the retardation of AgBr growth in pBr4, whereas the addition of DMT has a great restraining effect on the AgBr growth and the addition of CTAB accelerates AgBr growth by adsorbed C+. The possible explanation of the above-mentioned phenomena in AgBr recrystallization was also discussed.

Key words: photographic chemistry, silver bromide, crystal-growth modifiers, cetyl tri-methyl ammonium bromide, sodium dodecyls sulphate