Imaging Science and Photochemistry ›› 1991, Vol. 9 ›› Issue (3): 178-182.DOI: 10.7517/j.issn.1674-0475.1991.03.178

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STUDY ON INTERFACIAL KINETIC BEHAVIOURS OF Au MODIFIED CdSe THIN FILM ELECTRODES

ZHANG ZHI-WKI, LIN YUAN, XIAO XU-RUI   

  1. Institute of Photographic Chemistry, Academic Sinica, Beijing 100101, P. R. China
  • Received:1989-09-19 Revised:1990-12-04 Online:1991-08-20 Published:1991-08-20

Abstract: The transient photocurrent behaviours of Au modified CdSe thin film electrodes were studied in polysulfide solution.The reaction rate constants of interfacial heterogeneous charge transfer KF, surface charge recombination KR and photocorrosion Kc were estimated.Combining with the surface analysis of XPS and SEM, the interfacial kinetic behaviours of Au modified CdSe thin film electrodes were analysed.

Key words: Chemical modification, interfacial charge transfer, surface charge recombination, photocorrosion