STUDY OF PHOTOGRAPHIC PROPERTY OF GELATIN MACROMOLECULE Ⅲ. STUDY ON THE BINDING STATE BETWEEN IRON IONS AND GELATIN BY MOSSBAUER SPECTROSCOPY

doi:10.7517/j.issn.1674-0475.1993.03.193

Imaging Science and Photochemistry ›› 1993, Vol. 11 ›› Issue (3): 193-198.DOI: 10.7517/j.issn.1674-0475.1993.03.193

STUDY OF PHOTOGRAPHIC PROPERTY OF GELATIN MACROMOLECULE Ⅲ. STUDY ON THE BINDING STATE BETWEEN IRON IONS AND GELATIN BY MOSSBAUER SPECTROSCOPY

Li XUN, PENG BI-XIAN

Institute of Photographic Chemistry, Academia sinica, Beijing 100101, P. R. China

Received:1992-04-30 Revised:1992-12-10 Online:1993-08-20 Published:1993-08-20

Abstract

Abstract: In order to enrich the Iron ions, a gelatin sample solution was precipitated and concentrated via freeze drying method, and then was tested by a AME-50 Mossbauer Supec-trometer. It was shown that the trace Iron ions contained in gelatin sample (Fe²⁺, Fe³⁺) exist not in the free state, but are complex with the macromolecule. Different iron valence states are co-existed: Fe²⁺, Fe³⁺ and some interim valence between Fe²⁺ and Fe³⁺ caused by resonance structure, other special valence are also possible.

Key words: gelatin, Mossbauer spectrum, iron ion

Li XUN, PENG BI-XIAN. STUDY OF PHOTOGRAPHIC PROPERTY OF GELATIN MACROMOLECULE Ⅲ. STUDY ON THE BINDING STATE BETWEEN IRON IONS AND GELATIN BY MOSSBAUER SPECTROSCOPY[J]. Imaging Science and Photochemistry, 1993, 11(3): 193-198.

[1]	WANG Yihu, CAO Xiaofeng, ZHANG Bing, WANG Jianing, ZHANG Weijie, GUO Yanchuan. The Research Progress of Methacrylamide Gelatin Hydrogel [J]. Imaging Science and Photochemistry, 2020, 38(1): 22-26.
[2]	WANG Yihu, ZHANG Bing, MA Ming, LU Weipeng, WANG Jianing, GUO Yanchuan. Synthesis of GelMA/PEGDA Hydrogel by UV Photopolymerization [J]. Imaging Science and Photochemistry, 2017, 35(4): 574-580.
[3]	DENG Qiu, LI Youqun, TANG Shihua. Interaction Between ZnS Nanoparticles and Gelatin [J]. Imaging Science and Photochemistry, 2016, 34(4): 336-345.
[4]	WANG Baiyang, XIAO Xinguang, TANG Shihua, LIU Cen. The Thermodynamics of Gelatin/Fe₂S₃ Bionanocomposites Formation and Gelatin Conformational Change [J]. Imaging Science and Photochemistry, 2014, 32(6): 505-513.
[5]	YIN Liyan, CHEN Tiantian, ZHU Weiping. A Turn-on Fluorescent Probe for Fe³⁺ Based on Naphthalimide [J]. Imaging Science and Photochemistry, 2014, 32(1): 84-90.
[6]	SHI Li-li, SUN Huan-he, SHANG Zhuo-bin, WANG Yu. Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone [J]. Imaging Science and Photochemistry, 2013, 31(2): 132-139.
[7]	MA Ming, WANG Xue-song, ZHANG Bing, GUO Yan-chuan. Synthesis of Pure β-Ca₃(PO₄)₂ Bioceramics with Gelatin by Precipitation Method [J]. Imaging Science and Photochemistry, 2012, 30(4): 269-279.
[8]	JIANG Xiao-ming, SONG Lei, ZHAO Sui. Interaction Between Gemini Cationic Surfactants and Gelatin Investigated by Fluorescence [J]. Imaging Science and Photochemistry, 2012, 30(3): 175-181.
[9]	ZHANG Bing, SHI Jing-jing, WANG Ying, GUO Yan-chuan, CHEN Li-juan. Effect of Acid Pretreatment on IEP and Protein Patterns of Gelatin from the Bovine Bones by Protease-Conditioned Process [J]. Imaging Science and Photochemistry, 2012, 30(2): 102-109.
[10]	XIAO Xin-guang, LI You-qun, TANG Shi-hua. Study on the In Situ Binding of Nano-CoS to Gelatin [J]. Imaging Science and Photochemistry, 2011, 29(4): 297-305.
[11]	GE Jun, SUN Rui-xue, SHI Jing-jing, ZHANG Bing, CHEN Li-juan. Thermal Transition of Gelatin Microspheres with and Without Glutaraldehyde-Crosslinking [J]. Imaging Science and Photochemistry, 2009, 27(5): 334-341.
[12]	SUN Rui-xue, GUO Yan-chuan, ZHANG Bing, CHEN Li-juanCHEN Da-fu, SHI Rui, ZHOU Xin-hua. Studies on Hydroxyapatite Formation in Gelatin/Hydroxyapatite Composite Microspheres [J]. Imaging Science and Photochemistry, 2009, 27(5): 342-350.
[13]	TANG Shi-hua, HUANG Zai-yin. Biomimetic Synthesis of Acicular Nanometer HgS in the Gelatin Solution [J]. Imaging Science and Photochemistry, 2008, 26(3): 200-205.
[14]	TIAN Bao-zhu, TONG Tian-zhong, CHEN Feng, ZHANG Jin-long. Effects of Gelatin on Phase Transformation and Photocatalytic Activity of Nano-size Titanium Dioxide [J]. Imaging Science and Photochemistry, 2006, 24(2): 93-101.
[15]	TANG Shi-hua. Study of Interaction between Gelatin and Copper (Ⅱ) Using Synchronours Fluorescence Spectroscopy [J]. Imaging Science and Photochemistry, 2005, 23(2): 102-107.

STUDY OF PHOTOGRAPHIC PROPERTY OF GELATIN MACROMOLECULE Ⅲ. STUDY ON THE BINDING STATE BETWEEN IRON IONS AND GELATIN BY MOSSBAUER SPECTROSCOPY

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments