STUDY ON THE PHOTOSENSITIVITY OF SUPERFINES FERRUM COMPLEXES OF DITHIOLATE AND SUBSTITUTION-PHENANTHROLINE

doi:10.7517/j.issn.1674-0475.2001.04.268

Abstract

Abstract: The electronic absorption spectra and emission spectra of complexes FeLL′(L=mnt ^2-,1,2-dicyano-1,2-ethylenedithiolate or maleonitriledithiolate.L′=phen-5,6-dione,1,10-phenanthroline-5,6-dione;5-NO₂-phen,5 nitro-1,10-phenanthroline),and photosensitivity of CdS doped with FeLL′ are reported.The correlation between photosensitization of complexes FeLL′ to CdS and their electronic spectra is studied.

Key words: dithiolate, substitution phenanthroline, ferrum, complex, photosensitivity

CLC Number:

PAN Qing-cai, PENG Zheng-he. STUDY ON THE PHOTOSENSITIVITY OF SUPERFINES FERRUM COMPLEXES OF DITHIOLATE AND SUBSTITUTION-PHENANTHROLINE[J]. Imaging Science and Photochemistry, 2001, 19(4): 268-273.

References

[1] Meier H, Albrecht W, Kisch H, et al. Photoconductivity of nickel dithiolene with methyl viologen and other counteri ons[J]. J. Phys. Chem., 1989,93: 7726-7729.
[2] 彭正合,王政萍,倪小玲,等.锌(Ⅱ)双(马来腈二硫纶)电荷转移化合物的合成及其光电导和光敏性[J]功能材料,1998,39:183-185.Peng Z H,Wang Z P, Ni X L, et al. Synthesis, Photoconductivity and Photosensitivity of electron-transfer compoundsof zinc(Ⅱ)-bis(maleonitriledithiolene)complex[J]. J. Func. Mater., 1998,39:183-185.
[3] 潘庆才,任小明,彭正合,等.二氰基二硫纶@邻菲咯啉合钻(Ⅱ)掺杂CdS的光电导和光敏性研究[J].功能材料,1996,27(1):84-87.Pan Q C,Ren X M,Peng Z H, et al. Study of photoconductivity and photosensitivity of CdS doped with cobalt(Ⅱ)complexes of dicyanodithiolene and phenanthroline[J]. J. Func. Mater., 1996,27 (1):84-87.
[4] 彭正合,陈晓贵,潘庆才,等.超细粉体金属四氮杂卟啉网状聚合物的合成及其光敏化和对Li/SOCl₂电池的催化作用研究[J].武汉大学学报(自然科学版),2000,46(化学专刊):252-253.Peng Z H, Chen X G, Pan Q C, et al. Study on synthesis, photosensitization and electrocatalysis of superfines of two di mensional polymers of metal-porphyrazines with S2 and MS4 as the bridges[J]. J. Wuhan Univ. (Nat. Sci. Ed.),2000,46: 252-253.
[5] 彭正合,潘庆才,任小明,等.二氰基二硫纶和邻菲罗啉二酮的镍(Ⅱ)、铜(Ⅱ)、锌(Ⅱ)配合物的合成与性质[J]无机化学学报,1997,13(3):351-353.Peng Z H, Pan Q C, Ren X M, et al. Synthesis and Properties of nickel(Ⅱ), copper(Ⅱ) and zinc(Ⅱ) complexes with maleonitriledithiolate and 1,10-phenanthrolene-5,6-dione[J]. J. Inorg. Chem., 1997,13 (3):351-353.
[6] Peng Z H, Pan Q C, et al. Synthesis and spectroscopic characterization of transition metal complexes of maleoni triledithiolate and 5-nitro-phenanthroline[J].高等学校化学学报, 1998,19 (8, Suppl.): 377-378.Peng Z H, Pan Q C, et al. Synthesis and spectroscopic characterization of transition metal complexes of rmaleoni triledithiolate and 5-nitro-phenanthroline[J]. Chem. J. Chin. Univ., 1998,19 (8, Suppl.): 377-378.

[1]	XU Lina, YANG Lei, SHI Yarong, YUN Jia, JIN Qiuyan, PAN Qingyun, MIN Hao. Clinical Diagnostic Value of Multi-slice Spiral CT Post-processing Technique Applied to Sinus-nasal Complex Mutation and Sinusitis [J]. Imaging Science and Photochemistry, 2020, 38(6): 1052-1055.
[2]	ZHANG Zhansheng, GAO Yangchen, SHEN Dunpu, XIE Yinpeng, LI Ming, WANG Meng. Synthesis of Rare Earth Fluorescent Complexes Containing Europium and Their Applications in Latent Fingerprint Development [J]. Imaging Science and Photochemistry, 2018, 36(6): 498-506.
[3]	SUN Xiaojuan, WANG Zhiqiang, ZHANG Zhiqiang, XU Liancai. Synthesis,Structure and Photophysical Properties of a New Neutral Copper (Ⅰ) Complex [J]. Imaging Science and Photochemistry, 2018, 36(1): 64-72.
[4]	GUI Mengxi, YU Yang, ZHU Chengyi, LIU Hongfang, WANG Feng. Advances on Molecular Systems for Photocatalytic CO₂ Reduction Based on Cobalt Complexes as Catalysts [J]. Imaging Science and Photochemistry, 2017, 35(5): 649-657.
[5]	LIU Si, XIN Zhijuan, LEI Youjia, WANG Hongyan. Nickle Complex with[N₂O₂]-type Ligand for Electrochemical Hydrogen Production in Neutral Aqueous Solution [J]. Imaging Science and Photochemistry, 2017, 35(5): 765-770.
[6]	GAO Yunyan, CAI Wenjiao, OU Zhize, MA Tuotuo, WANG Ziji, XU Moheng. Detection of G-quadruplex by Supramolecular Systems Assembled by Perylenediimide Derivatives and Terpyridineplatinum(Ⅱ) Complexes [J]. Imaging Science and Photochemistry, 2017, 35(4): 552-562.
[7]	GAO Yunyan, WANG Zichao, OU Zhize, JU Baolong, HUANG Gan, FENG Zhao. The Effect of Substituent on the Temperature Sensitive Properties of Imidazo[4,5-f]-1,10-phenanthroline Ruthenium(Ⅱ) Complex [J]. Imaging Science and Photochemistry, 2015, 33(6): 468-478.
[8]	LI Shujing, ZHOU Ziruo, YUE Junzhi, ZHOU Wei, WANG Xinrui, BAI Dongsheng. Preparation and Photostability of the Inclusion Complex of HP-β-CD with Piceid [J]. Imaging Science and Photochemistry, 2015, 33(6): 487-493.
[9]	CHEN Jinping, DU Xinfeng, YU Tianjun, ZENG Yi, ZHANG Xiaohui, LI Yi. Homogeneous Photocatalytic Reduction of CO₂ under Visible Light Irradiation: Recent Developments and Future Challenges [J]. Imaging Science and Photochemistry, 2015, 33(5): 358-373.
[10]	CAI Rong, FU Wenfu. Highly Active CuO Water Oxidation Catalyst Electrodeposited from a Copper(Ⅱ) Complex [J]. Imaging Science and Photochemistry, 2015, 33(5): 403-410.
[11]	LIANG Wenjing, GAO Xuewang, XING Lingbao, MENG Qingyuan, ZHONG Jianji, LEI Tao, TONG Zhenhe, WU Lizhu. An Efficient Aerobic Cross-dehydrogenative-coupling Reaction Photocatalyzed by a Novel Platinum(Ⅱ) Terpyridyl Complex Under Visible Light [J]. Imaging Science and Photochemistry, 2014, 32(5): 447-454.
[12]	JIAO Yang, YAN Yuyu, HE Cheng, DUAN Chunying. Co^Ⅱ/Zn^Ⅱ Tetrahedron for Selectively Luminescent Recognition of ATP [J]. Imaging Science and Photochemistry, 2014, 32(1): 98-105.
[13]	LI Hai-xia, GAO Yun-yan, OU Zhi-ze, JIN He-lin, CAO Lu, CHEN Chen. Encapsulate Porphyrin or Fullerene Derivatives in PMADQUAT/PSt-PAA Polyion Complex Aggregates for Enhanced Singlet Oxygen Yields [J]. Imaging Science and Photochemistry, 2013, 31(3): 197-207.
[14]	FU Hua, HAN Ai-xia. The Preparation and Polarizing Property Studying in Modified Direct Gray D-Cu²⁺ Metal Complexes [J]. Imaging Science and Photochemistry, 2013, 31(3): 208-214.
[15]	WANG Ge-xia, FENG Ke, XING Ling-bao, SHI Xiao-yan, ZHANG Li-ping, TONG Zhen-ho(TUNG Chen-ho), WU Li-zhu. Photocatalytic Hydrogen Production Using a Cyclometalated 4-(4-Tolyl)-6-Phenyl-2,2'-Bipyridyl Platinum(Ⅱ) Chloride Complex [J]. Imaging Science and Photochemistry, 2013, 31(1): 18-23.