Photopolymerization of 4-Acryloylbenzophenone

doi:10.7517/j.issn.1674-0475.2008.01.32

Imaging Science and Photochemistry ›› 2008, Vol. 26 ›› Issue (1): 32-38.DOI: 10.7517/j.issn.1674-0475.2008.01.32

Previous Articles Next Articles

Photopolymerization of 4-Acryloylbenzophenone

ZHANG Hai-qing¹, XIAO Pu², DAI Ming-zhi¹, HE Yong¹, NIE Jun^1,2

1. The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2. Key Laboratory of Biomedical Polymers of Ministry of Education, Department of Chemistry, Wuhan University, Wuhan 430072, Hubei, P. R. China

Received:2007-06-20 Revised:2007-07-29 Online:2008-01-23 Published:2008-01-23

Abstract

Abstract: The kinetics of photopolymerization of 4-acryloylbenzophenone (4-ABP) was studied by Real-time Infrared spectroscopy,which showed that 4-ABP was a very effective photoinitiator.When the photoinitiator and amine were used to initiate polymerization of acrylates,both rate of polymerization and final conversion increased and the induction period shortened with increase of amine concentration,4-ABP concentration and light intensity.For it is crosslinked in the cured film,the amount of extracted 4-ABP is much lower than that of BP.

Key words: polymerizable photoinitiator, photopolymerization, kinetics, extractability, RT-IR

CLC Number:

ZHANG Hai-qing, XIAO Pu, DAI Ming-zhi, HE Yong, NIE Jun. Photopolymerization of 4-Acryloylbenzophenone[J]. Imaging Science and Photochemistry, 2008, 26(1): 32-38.

References

[1] 肖浦,吴刚强,史素青,等.基于α-羟烷基苯酮(HAPK)可聚合大分子光引发剂的合成及其引发三丙二醇双丙烯酸酯(TPGDA)光聚合动力学的研究[J].感光科学与光化学(影像科学与光化学),2006,5:204-210.Xiao P,Wu G Q,Shi S Q,et al.Synthesis of macrophotoinitiator based On HAPK and kinetics for photopolymerization of TPGDA[J].Photographic Science and Photochemistry(Imaging Science and Photochemistry),2006,5:204-210.
[2] Juan S,Norman A.Photochemistry and photoinduced chemical crosslinking activity of several type Ⅱ commercial photoinitiators in acrylated prepolymers[J].Journal of Photochemistry and Photobiology A:Chemistry,1999,122:115-125.
[3] 魏杰,金养智.光固化涂料[M].北京:化学工业出版社,2005.59-60.Wei J,Jin Y Z.UV-curable Coatings[M].Beijing:Chemical Industry Press,2005.59-60.
[4] 陈用烈,曾兆华,杨建文.辐射固化材料及其应用[M].北京:化学工业出版社,2003.130-142.Chen Y L,Zeng Z H,Yang J W.Radiant-curable Materials and Application[M].Beijing:Chemical Industry Press,2003.130-142.
[5] Wu G Q,Nie J.Synthesis and characterization of aliphatic amine co-initiator with different chain length for photopolymerization of dimethacrylate[J].Journat of Photochemistry and Photobiology A:Chemistry,2007,188:260-266.
[6] 金日光,华幼卿.高分子物理[M].第二版.北京:化学工业出版社,2000.103-112.JIn R G,Hua Y Q.Polymer Physics[M].2nd ed.Beijing:Chemical Industry Press,2000.103-112.
[7] Yu Q,Naurmm S,Smterte J P.UV photopolymerization behavior of dimethacrylate oligomers with eamphorquinone/amine initiator system[J].J.Appl.Polym.Sci.,2001,82(5):1107-1117.
[8] Decker C,Jenkins A D.Kinetic approach of oxygen inhibition in ultraviolet-and laser-induced polymerizations[J].Macromolecules,1985,18(6):1241-1244.

[1]	HU Xiangwu, ZHU Xiaoqun, NIE Jun, WANG Tao, XU Yanqing, LIU Yao. Preparation of Epoxy Microspheres by Continuous Photopolymerzation and Its Surface Functionalization [J]. Imaging Science and Photochemistry, 2020, 38(5): 771-779.
[2]	GAO Yang, SU Jiahui, LIU Xiaoxuan. Cationic Photopolymerization Kinetics of a Cycloaliphatic Diepoxide Using a Ferrocenium System Under UV-LED Exposure [J]. Imaging Science and Photochemistry, 2020, 38(2): 190-199.
[3]	ZHOU Jindi, LU Bingyu. Photopolymerization Properties of 1,2-Epoxy-4-epoxyethylcyclohexane Cationic Monomers [J]. Imaging Science and Photochemistry, 2020, 38(1): 37-45.
[4]	LI Xingzhou, HOU Zunyan, HE Yong. The Perparation and Application of Crosslinkable Fluorine-containing Particles via Photopolymerization in Supercritical Carbon Dioxide [J]. Imaging Science and Photochemistry, 2019, 37(5): 392-401.
[5]	PANG Yulian, ZHAO Liying, GAO Ming, ZOU Yingquan. Preparation and Properties of New Photoinitiator for UV-LED Photo Source [J]. Imaging Science and Photochemistry, 2019, 37(5): 438-444.
[6]	HAO Yajuan, LI Jingfang, LI Dongbing, YANG Jinliang, NIE Jun. Synthesis and Photopolymerization of Benzophenone Macromolecular Photoinitiators [J]. Imaging Science and Photochemistry, 2019, 37(5): 445-455.
[7]	XIE Gang, YANG Jianwen, ZHONG Rong. Study on Fluorocarbon Chain Modified Acyl Phosphine Oxide as Long Wavelength Absorbing Photoinitiator [J]. Imaging Science and Photochemistry, 2018, 36(5): 389-397.
[8]	CHEN Li, WU Qingyang, LIU Ren, LI Zhiquan. Deep Photopolymerization Research of Highly Stable Thiol-ene System [J]. Imaging Science and Photochemistry, 2018, 36(5): 408-416.
[9]	DONG Xiaoqing, LI Zhiquan, LIU Ren, LIU Xiaoya. Synthesis and Photochemical Properties of One-component Visible-light Photoinitiator Based on Photodecarboxylation [J]. Imaging Science and Photochemistry, 2018, 36(3): 226-235.
[10]	LI Cong, ZHANG Rongjin, YUAN Yan, LIU Ren. Preparation and Application of Ionic Liquid-ureido Pyrimidone Mixed Low Shrinkage Monomer [J]. Imaging Science and Photochemistry, 2018, 36(3): 254-266.
[11]	WANG Yihu, ZHANG Bing, MA Ming, LU Weipeng, WANG Jianing, GUO Yanchuan. Synthesis of GelMA/PEGDA Hydrogel by UV Photopolymerization [J]. Imaging Science and Photochemistry, 2017, 35(4): 574-580.
[12]	SHEN Weizhen, LIU Xiaoya, LIU Ren, LI Zhiquan. Synthesis and Photochemical Properties of Photobase Generators Containing Thioxanthone [J]. Imaging Science and Photochemistry, 2017, 35(1): 70-79.
[13]	ZHANG Na, CHEN Yuan, NIE Jun, YANG Jinliang. Research Progress of Cationic Reactive Diluents for Photopolymerization [J]. Imaging Science and Photochemistry, 2016, 34(6): 491-504.
[14]	JIAN Kai, LI Dongbing, ZHOU Jindi, YANG Jinliang, NIE Jun. Synthesis of Bifunctional One-component Photoinitiator and Its Initiatiating Activity [J]. Imaging Science and Photochemistry, 2016, 34(6): 505-512.
[15]	WANG Xiufeng, YANG Dong, LIU Minghua. Photochemical Reaction in Supramolecular Gels [J]. Imaging Science and Photochemistry, 2015, 33(1): 49-66.

Photopolymerization of 4-Acryloylbenzophenone

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments