Fabrication of Perylenetetracarboxyldiimide Film with Electrochemical Deposition Method

doi:10.7517/j.issn.1674-0475.2010.04.247

Abstract

Abstract: Electochemical deposition from solution is a film formation method with advantages of short deposition time and mild conditions. Thereby,obtaining solution of insoluble organic semiconductors(such as perylenetetracarboxyldiimide,PTCDI) for electro deposition is critical to getting their films.In this article,the dissolution process of PTCDI is confirmed by UVVis spectrum and electron spin resonance(ESR).Films of PTCDI 32,PTCDI 179 and composite films of these two are prepared from the solution of single PTCDI and mixture of the two by anode electro deposition,respectively.Characterization by UV-Vis,SEM and XRD show that the films have following characters: flat surfaces,reticular formation,controllable thickness and morphology,wide spectral absorption of the composite films.

Key words: perylenetetracarboxyldiimide, electochemical deposition, film

CLC Number:

MA Ning, ZHU Yuan-yuan, QIAN Ling-feng, XUE Min-zhao, SHENG Qiao-rong, ZHANG Qing, LIU Yan-gang. Fabrication of Perylenetetracarboxyldiimide Film with Electrochemical Deposition Method[J]. Imaging Science and Photochemistry, 2010, 28(4): 247-253.

References

[1] 沈永嘉,许煦,张忠胜.苝系颜料的品种与性能[J].化工科技市场,2001,24(6):10-13.Shen YJ,Xu X,Zhang Z S.Performance and applications of perylene pigments[J].Chemical Technology Mar-ket,2001,24(6):10-13.
[2] Alan MC,Aleksandra B D,Kai H T,et al.Organic nanoclusters oninorganic nanostructures for tailoring theemission properties of organic materials[J].Adv.Funct.Mater.,2008,18(4):566-574.
[3] Mihailetchi V D,Xie H X,Boer B,et al.Charge transport and photocurrent generation in poly(3-hexylthio-phene):methanofullerene bulk-heterojunction solar cells[J].Adv.Funct.Mater.,2006,16(5):699-708.
[4] Xue C M,Chen M Z,Shi J.Synthesis and characterization of the first soluble nonracemic chiral main-chainperylene tetracarboxylic dii mide polymers[J].Polymer,2008,49(24):5314-5321.
[5] Ya L L,Hong X L,De Y T,et al.Controlling the growth of single crystalline nanoribbons of copper tetracya-noquinodi methane for the fabrication of devices and devices arrays[J].J.Am.Chem.Soc.,2006,128(39):12917-12922.
[6] Yuji O,Eiji I,Keiichi M.Photovoltaic properties of phthalocyanine based p-n diode evaporated ontotitaniumdi-oxide[J].Thin Solid Fil ms,2006,499(1-2):369-373.
[7] Schlettwein D,Back A,Schilling B,et al.Ultrathinfil ms of perylenedianhydride and perylenebis(dicarboxi mi-de)dyes on(001)alkali halide[J].Chem.Mater.,1998,10(2):601-612.
[8] Marcon R O,Brochsztain S.Aggregation of 3,4,9,10-perylenedii mide radical anions and dianions generatedby reduction with dithionite in aqueous solutions[J].J.Phys.Chem.,2009,113(9):1747-1752.
[9] Gosztola D,Niemczyk MP,Svec W,et al.Excited doublet states of electrochemically generated aromatici mideand dii mide radical anions[J].J.Phys.Chem.,2000,104(28):6545-6551.
[10] Marcon R O,Brochsztain S.Highly stable 3,4,9,10-perylenedii mide radical anionsi mmobilizedin robust zir-coniumphosphonate self-assembled fil ms[J].Langmuir,2007,23(24):11972.
[11] Che Y,Datar A,Yang X M,et al.Enhancing one-di mensional charge transport throughintermolecularπ-elec-tron delocalization:conductivityi mprovement for organic nanobelts[J].J.Am.Chem.Soc.,2007,129(20):6354-6355.
[12] Frank W.Perylene bisi mide dyes as versatile building blocks for functional supramolecular architectures[J].Chem.Commun.,2004,(10):1564-1579.
[13] Pandey A K,Seignon S D,Nunzi J M.Pentacene:PTCDI-C₁₃H₂₇ molecular blends efficiently harvest light forsolar cell applications[J].Appl.Phys.Lett.,2006,89(11):113506.

[1]	ZHENG Xiangfei, SUN Xiaoxia, LIU Jingcheng, MU Qidao, LIU Ren, LIU Xiaoya. Research Progress of Chemically Amplified Photoresist Materials [J]. Imaging Science and Photochemistry, 2020, 38(3): 392-408.
[2]	WANG Jia, WANG Yali, HOU Lixin, LIU Xianhao. Design and Optimization of High-efficiency Perovskite Solar Cell Absorption Layer [J]. Imaging Science and Photochemistry, 2020, 38(3): 416-423.
[3]	LUO Dejun, YANG Bo. The Application of X-ray Plain Film and CT Scan in the Diagnosis of the Location and Anatomical Changes of Traumatic Vertebral Fracture [J]. Imaging Science and Photochemistry, 2020, 38(3): 464-469.
[4]	MA Chao. Non-destructive Testing Technology and Application [J]. Imaging Science and Photochemistry, 2020, 38(1): 46-51.
[5]	SHI Yan. Comparison of Diagnostic Efficacy of X-ray Plain Film, CT and MRI in Primary Bone Tumors of the Extremities [J]. Imaging Science and Photochemistry, 2019, 37(6): 571-577.
[6]	QI Yunpeng, ZHAO Xili, ZHOU Yajun, LI Yuhu, XING Huiping, WANG Yong, WU Nan. Effects of Acetic Acid Syndrome on Film Images [J]. Imaging Science and Photochemistry, 2019, 37(1): 57-64.
[7]	LIU Tingting, ZHU Tianxiang, SHAO Lin, ZHAO Xinluo, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Printed Carbon Nanotube Thin Film Transistors (TFTs) Based on Self-made Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2018, 36(3): 245-253.
[8]	LIU Lanlan, ZHOU Haihua, LI Lihong, ZHANG Xingye, SONG Yanlin. Fabrication of Transparent Conductive Films Based on Silver Nanowires and Their Applications in Printed Electronics [J]. Imaging Science and Photochemistry, 2018, 36(1): 33-50.
[9]	JIA Zhihui, LI Yuhu, SHI Meirong, XIE Lina, ZHOU Yajun. The Effect of Temperature and Humidity on the Physical Properties of Cellulose Acetate Film [J]. Imaging Science and Photochemistry, 2017, 35(6): 797-807.
[10]	Samuel Lascio, Hai-Feng Ji. Optical,Optoelectronic,and Photocatalytic Applications of Phosphorus Nanomaterials [J]. Imaging Science and Photochemistry, 2017, 35(5): 587-602.
[11]	QIN Changxi, NIU Juanni, GAO Chao. Study on Nano Metal Oxide Thermal Insulation Film and Properties [J]. Imaging Science and Photochemistry, 2017, 35(1): 80-87.
[12]	LUO Yan, ZHOU Yihua, QIAN Jun. Development of Transparent Conductive Films Based on Inkjet-printed Graphene [J]. Imaging Science and Photochemistry, 2016, 34(5): 482-490.
[13]	ZHANG Xiang, FEI Fei, GUO Wenrui, NIE Shuhong, WU Liangzhuan, XIE Jianjun, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Fully Printed Thin-film Transistors Based on PFO-DPP Sorted Semiconducting Single-walled Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2016, 34(2): 136-143.
[14]	XU Weiwei, XU Wenya, ZHANG Xiang, JIN Jing, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Ambipolar Thin Film Transistors(TFTs) Based on PFO-BT Sorted Semiconducting Single-walled Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2016, 34(2): 152-158.
[15]	LI Weijie, ZHOU Guangda, LI Bogeng. Preparation and Performance of UV-curing Waterborne Dry Film Photoresist Based on Acrylic Resins [J]. Imaging Science and Photochemistry, 2016, 34(2): 172-180.