用铜物理显影的多级放大成像过程Ⅲ.影像中铜和银的分布及明胶对Au3+的还原

doi:10.7517/j.issn.1674-0475.1994.01.1

影像科学与光化学 ›› 1994, Vol. 12 ›› Issue (1): 1-5.DOI: 10.7517/j.issn.1674-0475.1994.01.1

• 研究论文 • 下一篇

用铜物理显影的多级放大成像过程Ⅲ.影像中铜和银的分布及明胶对Au³⁺的还原

张宜恒¹, 庄思永¹, 谢绍銮¹, 韩新民¹, 任新民²

1. 中国科学技术大学近代化学系, 安徵合肥市 230026;
2. 中国科学院感光化学研究所, 北京 100101

收稿日期:1992-09-29 修回日期:1993-04-17 出版日期:1994-02-20 发布日期:1994-02-20
通讯作者: 张宜恒
基金资助:
国家自然科学基金

AN IMAGING PROCESS WITH MULII-STAGEAMPLIFlCATION BY COPPER PHYSHICAL DEVELOPMENT III.THE DISTRIBUTION OF COPPER AND SILVER WITHIN THE FINAL IMAGE AND THE REDUCTION OF Au³⁺ BY GELATIN IN NON-IMAGE AREA

ZHANG YI-HENG¹, ZHUANG SI-YONG¹, XIE SHAO-LUAN¹, HAN XIN-MIN¹, REN XIN-MIN²

1. Department of Modern Chemistry, University of Science and Technology of China, Hefei 230026, Anhui P. R. China;
2. Institute of Photographic Chemistry, Academia Sinica, Beijing 100101, P. R. China

Received:1992-09-29 Revised:1993-04-17 Online:1994-02-20 Published:1994-02-20

摘要/Abstract

摘要： 本文研究了铜物理显影后影像中铜和银的分布以及在非影像区明胶对Au³⁺的还原作用。铜含量随着影像深度的增加而增加,银含量却随着深度的增加而减少。Ag3d结合能向低值位移说明影像内部的银处于单原子和多原子的混合状态,但是影像表面的银却为单原子状态,如果铜物理显影进行得足够长,铜最终会将银全部遮盖。在这以后的铜物理显影是铜的自催化过程,样片浸入氯金酸溶液中后,非影像区中吸收的氯金酸量大大高于影像区,因而铜的沉积速度在非影像区也比影像区大得多。明胶能还原Au³⁺.还原过程可分为两步:第一步由Au³⁺还原成Au⁺,这一步在室温下是快反应;第二步由Au⁺还原成金,这个反应比较慢,Au⁺和Au在物理显影中可作为催化核,使铜在非影像区沉积。

关键词: 铜物理显影, 电子衍射, X射线光电子能谱, Au³⁺的还原

Abstract: The distribution of copper and silver within the final image obtained by copper phys-ical development and the reduction of Au³⁺ by gelatin in non-image area were studied.Itwas indicated that the copper content increases with the increase of depth,whereas the sil-ver content decreases with the increase of depth,The shift of the bind energy of Ag3d to alow value shows that the silver in the interior of the image is in a mixed state of monoatomsand polyatoms,but the silver at the image surface is exclusively in a monoatomic state.Ifthe time of copper physical development is long enough,copper will completely cover silver.From then on the copper physical development continues because of the autocatalysis ofnewly formed copper.It was shown that much more chloroauric acid was absorbed in thenon-image area and hence the deposition speed of copper was much faster than that in theimage area.Gelatin can reduce Au³⁺.The reduction process might be divided into twosteps.The first step, which is fast at the room temperature,is the formation of Au⁺,andthe second step,which is relatively slow,is the formation of gold.Au⁺ and gold mightact as catalytic nuclei during the copper physical development depositing copper in thenon-image area.

Key words: copper Physical development, electron diffraction, X-ray photoelectronspectroscopy, reduction of Au³⁺

张宜恒, 庄思永, 谢绍銮, 韩新民, 任新民. 用铜物理显影的多级放大成像过程Ⅲ.影像中铜和银的分布及明胶对Au³⁺的还原[J]. 影像科学与光化学, 1994, 12(1): 1-5.

ZHANG YI-HENG, ZHUANG SI-YONG, XIE SHAO-LUAN, HAN XIN-MIN, REN XIN-MIN. AN IMAGING PROCESS WITH MULII-STAGEAMPLIFlCATION BY COPPER PHYSHICAL DEVELOPMENT III.THE DISTRIBUTION OF COPPER AND SILVER WITHIN THE FINAL IMAGE AND THE REDUCTION OF Au³⁺ BY GELATIN IN NON-IMAGE AREA[J]. Imaging Science and Photochemistry, 1994, 12(1): 1-5.

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用铜物理显影的多级放大成像过程Ⅲ.影像中铜和银的分布及明胶对Au³⁺的还原

AN IMAGING PROCESS WITH MULII-STAGEAMPLIFlCATION BY COPPER PHYSHICAL DEVELOPMENT III.THE DISTRIBUTION OF COPPER AND SILVER WITHIN THE FINAL IMAGE AND THE REDUCTION OF Au³⁺ BY GELATIN IN NON-IMAGE AREA

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