蛋氨酸与化学增感剂的相互作用机理

doi:10.7517/j.issn.1674-0475.2001.01.19

影像科学与光化学 ›› 2001, Vol. 19 ›› Issue (1): 19-28.DOI: 10.7517/j.issn.1674-0475.2001.01.19

蛋氨酸与化学增感剂的相互作用机理

张宜恒¹, 冯少红¹, 闫天堂¹, 宫竹芳², 俞书勤³, 庄思永⁴, 彭必先⁵

1. 中国科学技术大学应用化学系合肥 230026;
2. 中国科学技术大学近代物理系合肥 230026;
3. 中国科学技术大学化学物理系, 合肥 230026;
4. 华东理工大学精细化学品研究所, 上海 200237;
5. 中国科学院理化技术研究所, 北京 100101

收稿日期:2000-07-05 修回日期:2000-09-27 出版日期:2001-02-20 发布日期:2001-02-20
通讯作者: 张宜恒
基金资助:
家自然科学基金资助项目(29876038)

THE INTERACTION MECHANISM OF METHIONINE AND CHEMICAL SENSITIZERS

ZHANG Yi-heng¹, FENG Shao-hong¹, GONG Zhu fang 1¹, YAN Tian-tang², YU Shu-qin 2 (Department of Applied Chemistry³, 1 Department of Modern Physics⁴, 2 Department of Chemical Physics⁵

Received:2000-07-05 Revised:2000-09-27 Online:2001-02-20 Published:2001-02-20

摘要/Abstract

摘要： 运用X射线光电子能谱(XPS)的ESCA扫描技术研究了蛋氨酸与不同化学增感剂相互作用及其中的硫、金、碳和氧等元素的化学形态和相对含量的变化规律.发现蛋氨酸与不同的化学增感剂的反应机理是不尽相同的.蛋氨酸与S增感剂不会发生任何化学反应,它们可以稳定地共存于同一体系之中;蛋氨酸可以将全部Au^3＋增感剂还原为Au,其自身部分被氧化为蛋氨酸亚砜,并且在其脱质子的羟基部位与Au形成Au-O-C结构的金属配合物.向蛋氨酸体系中加入S＋Au增感剂后,体系中的氧化还原反应发生在外加的Au^3＋和S₂O₃^2－之间,此时蛋氨酸的作用是将被S增感剂还原的Au络合,亦形成Au-O-C结构的配合物.

关键词: 蛋氨酸, 化学增感剂, X射线光电子能谱

Abstract: The changes of the chemical states and the relative contents of sulfur, gold, carbon and oxygen after methionine reacted with different chemical sensitizers are studied by ESCA scanning technique of X-ray Photoelectron Spectroscopy(CPS). The results indicated that the interaction mechanism of methionine reacted with different chemical sensitizers is not identical. Any oxidation-reduction reaction did not occurred between methionine and sulfur sensitizer, they could coexist steadily in the same system. The methionine was oxidized to methionine sulfoxide, in the same time reducing Au³⁺ to gold atom. The hydroxy of methionine could coordinate Au, forming Au-O-C coordinate metal complex. After S⁺Au sensitizers had been immersed into methionine system, oxidation-reduction reaction occurred between added thiosulfate and Au³⁺, methionine could coordinate Au which was reduced by sulfur sensitizer, also forming Au-O-C coordinate metal complex.

Key words: methionine, chemical sensitizer, X-ray photoelectron spectroscopy

中图分类号:

TQ57

张宜恒, 冯少红, 闫天堂, 宫竹芳, 俞书勤, 庄思永, 彭必先. 蛋氨酸与化学增感剂的相互作用机理[J]. 影像科学与光化学, 2001, 19(1): 19-28.

ZHANG Yi-heng, FENG Shao-hong, GONG Zhu fang 1, YAN Tian-tang, YU Shu-qin 2 (Department of Applied Chemistry, 1 Department of Modern Physics, 2 Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R.. THE INTERACTION MECHANISM OF METHIONINE AND CHEMICAL SENSITIZERS[J]. Imaging Science and Photochemistry, 2001, 19(1): 19-28.

参考文献

[1] Clercq M De.Photographic gelatin production[J].J.Imaging Sci.& Tech.,1995,39(4):36.
[2] Zhang Y H,Tan J,Li J,et al.The interaction between photographic gelatins and chemical sensitizers[J].J.Imaging Sci.& Tech.,2000,44(2):164.
[3] James T H.The Theory of the Photographic Process[M].4th Edition.New York:Macmillan Publishing Co.Inc.,1977.
[4] Tani S,Tani T.Determination of methionine and its oxudes in gelatin[J].J.Photogr.Sci.,1993,41:172.
[5] Li X,Peng B X.The determination of Methionine,methionine sulphoxide and methionine sulphone contained in photographic gelatins[J].J.Photogr.Sci.,1992,40:149.
[6] Zhang Y H,Li J,Yan T T,et al.Study of the chemical state of sulfur in photographic gelatin by XPS[J].J.Imaging Sci.& Tech.,1999,43(1):49.
[7] 张宜恒,谭戟,闫天堂,等.照相明胶与化学增感剂相互作用的XPS研究[J].感光科学与光化学,1999,17(2):120.Zhang Y H,Tan J,Yan T T,et al.Study of the interaction between photographic gelatins and chemical sensitizers by XPS[J].Photographic Science and Photochemistry,1999,17(2):120.
[8] Wagner C D.Handbook of X-ray Photoelectron Spectroscopy[M].Minnesuta:Perkin-Elmer Corporation,1979.
[9] 张兵,王流芳,陈忠林.吲哚-3-羧酸、Nd(Ⅲ)、邻菲咯啉配合物结构XPS研究[J].化学物理学报,1997,10(3):265.Zhang B,Wang L F,Chen Z L.Study of complexes of neodymium(Ⅲ) with indole-3-carboxylic acids and 1,10-phenanthroline by XPS[J].Chinese Journal of Chemical Physics,1997,10(3):265.
[10] Brisk M A.Shake-up satellites in X-ray photoelectron spectroscopy[J].J.Electron Spectrosc.Relat.Phenom.,1975,7:197.
[11] 王建祺,吴文辉,冯大明.电子能谱学引论[M].北京:国防工业出版社,1992.Wang J Q,Wu W H,Feng D M.Introduction to Electron Spectroscopy[M].Beijing.National Defence Industry Press,1992.
[12] Gerenser L J.An X-ray photoelectron spectroscopy study of chemical interaction at silver/plasma modified polyethylene interfaces:correlation with adhesion[J].J.Vac.Sci.Tech.,1988,A6(5):2897.
[13] Fadley C S.In:Brundle C R,Baker A D,eds.Basic Concepts of X-ray Photoelectron Spectroscopy,in Electron Spectroscopy:Theory,Techniques and Applications[M].Vol.2.London:Academic Press,1978.154-156.

蛋氨酸与化学增感剂的相互作用机理

THE INTERACTION MECHANISM OF METHIONINE AND CHEMICAL SENSITIZERS

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 10

编辑推荐

Metrics

本文评价

[1]	李东芹, 黄碧霞, 岳军, 周涛. 明胶与Ag⁺相互作用的XPS研究[J]. 影像科学与光化学, 2004, 22(3): 169-174.
[2]	史京京, 滕淑华, 吴珊, 彭必先, 陈丽娟, 倪景华. 氯化银T-颗粒乳剂制备专用的氧化明胶的研究[J]. 影像科学与光化学, 2004, 22(1): 13-19.
[3]	郑彤, 李智, 彭必先, 陈丽娟, 陈晶. 明胶中蛋氨酸含量对氯化银{100}面T-颗粒乳剂晶形的影响[J]. 影像科学与光化学, 2003, 21(6): 401-404.
[4]	张宜恒, 谭戟, 闫天堂, 俞书勤, 庄思永, 彭必先. 照相明胶与化学增感剂相互作用的XPS研究[J]. 影像科学与光化学, 1999, 17(2): 120-127.
[5]	张宜恒, 李洁, 闫天堂, 俞书勤, 庄思永, 彭必先. 照相明胶中硫存在形态的XPS研究[J]. 影像科学与光化学, 1998, 16(4): 314-320.
[6]	熊良文, 黄惠忠, 彭必先. 曝光-显影的时间间隔对重铬酸盐明胶全息性能影响的研究[J]. 影像科学与光化学, 1998, 16(1): 43-47.
[7]	张宜恒, 庄思永, 谢绍銮, 韩新民, 任新民. 用铜物理显影的多级放大成像过程Ⅲ.影像中铜和银的分布及明胶对Au³⁺的还原[J]. 影像科学与光化学, 1994, 12(1): 1-5.
[8]	李迅, 彭必先, 肖玉霞, 倪景华. 明胶大分子的照相性质研究——Ⅰ.明胶中的蛋氨酸砜及亚砜的测定[J]. 影像科学与光化学, 1993, 11(2): 40-44.
[9]	李迅, 彭必先. 明胶大分子的照相性质研究 Ⅱ.明胶中蛋氨酸及其氧化物对明胶还原性影响的研究[J]. 影像科学与光化学, 1993, 11(2): 45-48.
[10]	张志伟, 肖绪瑞, 孙璧媃. cdSe_xTe_1-x薄膜电极光溶解性能的研究[J]. 影像科学与光化学, 1990, 8(2): 113-120.