影像科学与光化学 ›› 2004, Vol. 22 ›› Issue (4): 251-258.DOI: 10.7517/j.issn.1674-0475.2004.04.251

• 研究论文 • 上一篇    下一篇

有序纳米金颗粒的多层组装

周学华1, 刘春艳1, 张志颖1, 江龙2, 李津如2   

  1. 1. 中国科学院理化技术研究所, 北京, 100101;
    2. 中国科学院化学研究所, 北京, 100080
  • 收稿日期:2004-03-19 修回日期:2004-03-31 出版日期:2004-07-23 发布日期:2004-07-23
  • 通讯作者: 刘春艳(1947-), 女, 研究员, 博士生导师, 主要从事分散体系化学与光化学和纳米光功能材料的研究.

Assemblage of Ordered Nanogolds

ZHOU Xue-hua1, LIU Chun-yan1, ZHANG Zhi-ying1, JIANG Long2, LI Jin-ru2   

  1. 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P.R. China;
    2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P.R. China
  • Received:2004-03-19 Revised:2004-03-31 Online:2004-07-23 Published:2004-07-23

摘要: 采用LB技术组装了一种三维有序的由十八胺修饰的纳米金颗粒多层结构.这是一种新的组装纳米颗粒三维有序聚集体的方法.为了扩大这种方法的适用范围,在组装过程中,将有机小分子1-苯基-5-巯基四氮唑引进结构,形成了新的纳米金颗粒多层聚集体.这两种多层膜经透射电子显微镜和小角X射线衍射测量证明构成多层膜的单层膜上的纳米金颗粒是有序的,并且颗粒在层与层之间的排列也是有序的.

关键词: LB技术, 多层组装, 有序纳米金颗粒

Abstract: Octadecylamine coated-nanogolds formed a three-dimensional ordered structure by LB technique.This was a new method to construct three-dimensional ordered aggregates.In order to enlarge the usage of the method,during the construction,organic small molecule,1-phenys-5-mecaptotetrazole was assembled into the interlayers,a new multilayer was formed.The two multilayers had ordered particles both on planes and in layer by layer,which were confirmed by TEM images and small-angle X-ray diffraction measurement.

Key words: Langmuir-Blodgett technique, assemble, ordered nanogolds

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