新型联苯醌衍生物静电照相性能的研究

doi:10.7517/j.issn.1674-0475.2006.04.286

影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (4): 286-290.DOI: 10.7517/j.issn.1674-0475.2006.04.286

新型联苯醌衍生物静电照相性能的研究

贾志梅, 张伟民, 吴倜, 王文广, 蒲嘉陵

北京印刷学院, 印刷包装材料与技术北京市重点实验室, 北京, 102600

收稿日期:2006-03-16 修回日期:2006-05-08 出版日期:2006-07-23 发布日期:2006-07-23

Study on Xerographic Performances of Diphenoquinone Derivatives

JIA Zhi-mei, ZHANG Wei-min, WU Ti, WANG Wen-guang, PU Jia-ling

Lab.Printing & Packaging Material and Technology, Beijing Institute of Graphic Communication, Beijing 102600, P.R. China

Received:2006-03-16 Revised:2006-05-08 Online:2006-07-23 Published:2006-07-23

摘要/Abstract

摘要： 本研究合成了一系列联苯醌衍生物并对其结构进行确认,同时以合成的联苯醌衍生物作为电子传输材料(ETM)与空穴传输材料(HTM)、电荷产生材料(CGM)和成膜树脂进行匹配,制备了多组分掺杂的单层结构有机光导体.研究结果表明,光导体的感光度强烈地依赖于ETM的掺杂浓度,半衰曝光量首先随ETM浓度的增大而减小,在掺杂浓度为10%时降到最小,并趋于稳定.2,5,5′-三叔丁基联苯醌在所研究的联苯醌衍生物中性能最为优秀,在780 nm处半衰曝光量为2.2μJ/cm².

关键词: 联苯醌衍生物, 光导体, 静电照相性能

Abstract: A series of diphenoquinone derivatives were synthesized and their molecular structures were confirmed by using CLT,IR,NMR and MS.The diphenoquinone derivative used as ETM was doped along with other components,e.g.,HTM and CGM,into a polymer matrix,to form a single-layered organic photoreceptor.It was found that photosensitivity was strongly dependent on ETM concentration.The half decay exposure firstly decreased with ETM’s concentration and then increased at higher ETM concentrations after having reached a minimum at 10%,and finally a plateau was reached after that.2,5,5′-tritert-butyl diphenoquione was found the best among other investigated diphenoquinone derivatives and the half decay exposure was 2.2 μJ/cm² at 780 nm wavelength.

Key words: diphenoquinone, organic photoreceptor, xerographic performance

中图分类号:

TQ57

贾志梅, 张伟民, 吴倜, 王文广, 蒲嘉陵. 新型联苯醌衍生物静电照相性能的研究[J]. 影像科学与光化学, 2006, 24(4): 286-290.

JIA Zhi-mei, ZHANG Wei-min, WU Ti, WANG Wen-guang, PU Jia-ling. Study on Xerographic Performances of Diphenoquinone Derivatives[J]. Imaging Science and Photochemistry, 2006, 24(4): 286-290.

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新型联苯醌衍生物静电照相性能的研究

Study on Xerographic Performances of Diphenoquinone Derivatives

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