1,8-二(2-羟乙基)亚氨基蒽醌荧光探针用于Fe3+的高选择性测定

doi:10.7517/j.issn.1674-0475.2013.02.006

影像科学与光化学 ›› 2013, Vol. 31 ›› Issue (2): 132-139.DOI: 10.7517/j.issn.1674-0475.2013.02.006

1,8-二(2-羟乙基)亚氨基蒽醌荧光探针用于Fe³⁺的高选择性测定

时丽丽, 孙欢鹤, 尚卓镔, 王煜

山西大学化学化工学院, 山西太原 030006

收稿日期:2012-09-04 修回日期:2012-11-01 出版日期:2013-03-15 发布日期:2013-03-15
通讯作者: 王煜,E-mail:wangyu1168@sxu.edu.cn.
基金资助:
山西省回国留学人员科研资助项目(2011-008)

Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone

SHI Li-li, SUN Huan-he, SHANG Zhuo-bin, WANG Yu

School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, Shanxi, P.R. China

Received:2012-09-04 Revised:2012-11-01 Online:2013-03-15 Published:2013-03-15

摘要/Abstract

摘要： 在蒽醌荧光团上修饰乙醇胺分子,合成了用于铁离子识别检测的新的荧光探针.实验结果表明,在乙醇:水=4:1,pH值为7.20的条件下,Fe³⁺的加入使体系荧光猝灭,荧光强度和Fe³⁺浓度在4.0×10^-5-3.0×10^-4 mol/L范围内呈线性关系,由此可以实现在乙醇/水体系中对Fe³⁺离子的高选择性检测.检测限为3.8×10^-7mol/L.

关键词: 蒽醌, 荧光, 探针, Fe³⁺, 测定

Abstract: A new fluorionophore, which is composed of anthraquinone and a hydroxyl ethanol-amine receptor, has been synthesized. Effect of metal ions on the fluorescence of the ionophore was investigated. The results show that the ionophore displays a highly selective and sensitive response of fluorescence quenching toward Fe³⁺ in neutral buffer aqueous solution. There is a good linear relationship between the fluorescence intensity and Fe³⁺ concentration in the range of 4.0?10^-5-3.0?10^-4 mol/L. The detection limit is 3.8?10^-7 mol/L.

Key words: anthraquinone, fluorescence, probe, iron ions, sensing

中图分类号:

时丽丽, 孙欢鹤, 尚卓镔, 王煜. 1,8-二(2-羟乙基)亚氨基蒽醌荧光探针用于Fe³⁺的高选择性测定[J]. 影像科学与光化学, 2013, 31(2): 132-139.

SHI Li-li, SUN Huan-he, SHANG Zhuo-bin, WANG Yu. Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone[J]. Imaging Science and Photochemistry, 2013, 31(2): 132-139.

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1,8-二(2-羟乙基)亚氨基蒽醌荧光探针用于Fe³⁺的高选择性测定

Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone

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