THERMODYNAMIC PROPERTIES OF SELF-ASSOCIATION OF PHOTOGRAPHIC SPECTRAL SENSITIZING CYANINE DYES Ⅱ. J-AGGREGATE FORMATION OF 3,3’-DI-(r-SULFOPROPYL)-9-ETHYL-4,5,4’,5’-DIBENZOTHIA-CARBOCYANINE IN DMF-H2O MIXED SOLVENTS AND HEAT OF J-AGGREGATION MEA

doi:10.7517/j.issn.1674-0475.1989.04.25

Imaging Science and Photochemistry ›› 1989, Vol. 7 ›› Issue (4): 25-30.DOI: 10.7517/j.issn.1674-0475.1989.04.25

Previous Articles Next Articles

THERMODYNAMIC PROPERTIES OF SELF-ASSOCIATION OF PHOTOGRAPHIC SPECTRAL SENSITIZING CYANINE DYES Ⅱ. J-AGGREGATE FORMATION OF 3,3’-DI-(r-SULFOPROPYL)-9-ETHYL-4,5,4’,5’-DIBENZOTHIA-CARBOCYANINE IN DMF-H₂O MIXED SOLVENTS AND HEAT OF J-AGGREGATION MEA

GONG YONG-KUAN, SHEN JIE-RU, ZHONG GUANG-XUE, ZHANG ZU-XUN

Chemistry Department, the Northwest University, Xian 710069, P.R. China

Received:1988-04-23 Revised:1988-11-16 Online:1989-11-20 Published:1989-11-20

Abstract

Abstract: Results were reported for the study of J-aggregation of 3, 3’-di-(r-sulfopropyl)-9-ethyl-4, 5,4’,5’-dibenzothia-carbocyanine triethylamine salt (I) on adding KBr to its solutions in DMF-H₂O mixed solvents, where only dimer monomer equilibrium of the dye existed. Heat effects of the mentioned mainly J-aggregate forming processes were measured directly and the J-aggregation enthalpy, △H_s, expressed as the mean aggregation enthalpy per monomer unit (i.e. the-average enthalpy change if one monomer is associated to a growing J-aggregate) was obtained. J-aggregation number was estimated to be 6.

Key words: cyanine, photographic spectral sensitizing dye, J-aggregates, enthalpy of aggregation

GONG YONG-KUAN, SHEN JIE-RU, ZHONG GUANG-XUE, ZHANG ZU-XUN. THERMODYNAMIC PROPERTIES OF SELF-ASSOCIATION OF PHOTOGRAPHIC SPECTRAL SENSITIZING CYANINE DYES Ⅱ. J-AGGREGATE FORMATION OF 3,3’-DI-(r-SULFOPROPYL)-9-ETHYL-4,5,4’,5’-DIBENZOTHIA-CARBOCYANINE IN DMF-H₂O MIXED SOLVENTS AND HEAT OF J-AGGREGATION MEA[J]. Imaging Science and Photochemistry, 1989, 7(4): 25-30.

[1]	MA Yaguang, ZHANG Yutao, MA Yiyu, GUO Zhiqian, ZHU Weihong. Near-infrared Cyanine-based Fluorescent Probe for Cysteine with High Selectivity [J]. Imaging Science and Photochemistry, 2018, 36(3): 236-244.
[2]	CUI Lixia, ZHANG Honghong, LI Miao, ZHANG Caihong, ZHANG Guomei, SHUANG Shaomin, DONG Chuan. Preparation and Spectral Characterization of a pH Ratiometric Fluorescence Probe [J]. Imaging Science and Photochemistry, 2018, 36(3): 283-290.
[3]	YU Danping, LIU Yawei, SHEN Liang, LI Fuyou. Cyanine Dye-loading Polymer Nanoparticle for Colorimetric Detection of Hypochlorous Acid [J]. Imaging Science and Photochemistry, 2017, 35(3): 290-296.
[4]	ZHU Dongjian, JIANG Hua. Cyanine-based Near-infrared Ratiometric Fluorescent Probe for Thiols [J]. Imaging Science and Photochemistry, 2014, 32(1): 106-112.
[5]	CHEN Xiu-ying, GUO Lin, JIA Xian-lin, GAO Hai-yan, ZHENG Chang-ge. Synthesis, Characterization and Spectral Properties of Novel Meso-Substituted Heptamethine Cyanine Dye [J]. Imaging Science and Photochemistry, 2012, (5): 375-383.
[6]	LIU Hong, ZHENG Ke, LI Jun, CAI Li-xuan, FANG Yu-ting, XUE Jin-ping. Study on Photosensitive Oxidation Ability of Metallophthalocyanines on Tryptophan [J]. Imaging Science and Photochemistry, 2012, 30(2): 124-128.
[7]	QIAN Ling-feng, ZHANG Jia, XUE Min-zhao, ZHU Yuan-yuan, ZHANG Qing, LIU Yan-gang. Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine [J]. Imaging Science and Photochemistry, 2011, 29(2): 114-122.
[8]	WEI Yan, CHEN Wei, WANG Yu, LI Tao, BI Cheng, XIA Chun-hui. Photoinhibition on Liver Cancer Cell of Amphiphilic Phthalocyanine Zinc [J]. Imaging Science and Photochemistry, 2010, 28(5): 362-367.
[9]	MAMUT Mariya, MAHMUT Mamtimin, MAHMUT Melikizat, YIMIT Abliz, RAHMAN Adalet. Study of Optical Waveguide Sensing Element for Nitrogen Dioxide Detection [J]. Imaging Science and Photochemistry, 2010, 28(2): 104-110.
[10]	FAN Ji-min, ZHAO Zhi-huan, WANG Zhi-zhong. Preparation of Titania-based CoPc Catalysts for CO₂ Photocatalytic Reduction by the In-situ Method [J]. Imaging Science and Photochemistry, 2009, 27(4): 263-272.
[11]	CHEN Xiu-ying, ZHAO Xiao-qin, ZHENG Chang-ge. Research on Synthesis and Properties of Novel 3H-indolenine Fluorescent Cyanine Dyes [J]. Imaging Science and Photochemistry, 2008, 26(4): 291-298.
[12]	YANG Shao-peng, LI Chun-lei, FAN Shan-shan, LI Xiao-wei, FU Guang-sheng. Ultrafast Kinetics Characteristics of Fluorescence in Anionic-Cationic Cyanine Dyes [J]. Imaging Science and Photochemistry, 2007, 25(5): 364-373.
[13]	LUO Qian, XUE Min-zhao, ZHANG Qing, SHENG Qiao-rong, LIU Yan-gang. Research on Polymorph of Copper Phthalocyanine and Preparation of its Ultrafine Particles [J]. Imaging Science and Photochemistry, 2007, 25(4): 275-283.
[14]	HUANG Xin, LI Zhong-yu, BIN Yue-jing, HUANG Lei, ZHANG Fu-shi. Study on Synthesis and Spectral Properties of Phthalocyanine Conjugating Luminols [J]. Imaging Science and Photochemistry, 2007, 25(3): 209-213.
[15]	HUANG Lei, BIN Yue-jing, HUANG Xin, ZHANG Fu-shi. Studies on the Acid-Generation Properties of a New Phthalocyanine Derivative as Photoetching Recording Materials [J]. Imaging Science and Photochemistry, 2007, 25(2): 142-146.

THERMODYNAMIC PROPERTIES OF SELF-ASSOCIATION OF PHOTOGRAPHIC SPECTRAL SENSITIZING CYANINE DYES Ⅱ. J-AGGREGATE FORMATION OF 3,3’-DI-(r-SULFOPROPYL)-9-ETHYL-4,5,4’,5’-DIBENZOTHIA-CARBOCYANINE IN DMF-H₂O MIXED SOLVENTS AND HEAT OF J-AGGREGATION MEA

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments