Study of Optical Waveguide Sensing Element for Nitrogen Dioxide Detection

doi:10.7517/j.issn.1674-0475.2010.02.104

Abstract

Abstract: An optical waveguide sensing element was prepared by spin coating a thin film of copper phthalocyanine(CuPc) onto the surface of K⁺-ion exchanged optical waveguide which was prepared by hot ion-exchanged method,and nitrogen dioxide was detected successfully using this sensing element in optical waveguide gas sensor system.The experimental results showed that this sensing element has reversible response to nitrogen dioxide gas with highly sensitivity and good reproducibility.

Key words: copper phthalocyanine, thin film, optical waveguide gas sensor, nitrogen dioxide

CLC Number:

MAMUT Mariya, MAHMUT Mamtimin, MAHMUT Melikizat, YIMIT Abliz, RAHMAN Adalet. Study of Optical Waveguide Sensing Element for Nitrogen Dioxide Detection[J]. Imaging Science and Photochemistry, 2010, 28(2): 104-110.

References

[1] 金兴良,李伟,孙大海,等.二氧化氮化学膜传感器[J].传感技术学报,2001,4:259-264.Jin X L,Li W,Sun D H,et al.The Thin Film sensors for Nitrogen Dioxide[J].Chinese Journal of Sensors and Actuators,2001,4:259-264.
[2] Potyrailo R A,Hobbs S E,Hieftje G M.Optical waveguide sensors in analytical chemistry:today's instrumentation,applications and trends for future development[J].Fresenius Journal of Analytical Chemistry,1998,362(4):349-373.
[3] Yimit A,Rossberg A G,Amemiya T,et al.Thin film composite optical waveguides for sensor applications[J].Talanta,2005,65(5):1102-1109.
[4] Ablat H,Yimit A,Mahmut M,et al.Nafion film/K+-exchanged glass optical waveguide sensor for BTX detection[J].Analytical Chemistry,2008,80(20):7678-7683.
[5] Kader R,Yimit A,Hayrensa A,et al.Optical waveguide BTX gas sensor based on poly acrylate resin thin film[J].Environ.Sci.Technol.,2009,43:5113-5116.
[6] Bott B,Jones T A.A highly sensitive NO₂ sensors based on electrical conductivity changes in phthalocyanine films[J].Sensors and Actuators,1984,5:43-53.
[7] Jones T A,Bott B.Gas-induced electrical conductivity changes in metalphthalocyanines[J].Sensors and Actuators,1986,9:27-37.
[8] Ramaswamy R V,Sriwastave R J.Ion-exchanged glass waveguides:A review[J].Lightwave Technol.,1988,6(6):984-1002.
[9] 玛丽娅·马木提,麦麦提依明·马合木提,阿不力孜·伊米提,等.光波导乙醇气体传感器的研究[J].影像科学与光化学,2008,4(26):285-290.Mamut M,Mahmut M,Yimit A,et al.Fabrication of the optical waveguide ethanol gas sensor[J].Imaging Science and Photochemistry,2008,4(26):285-290.
[10] 陈启婴,顾冬红,何胡玲,等.酞菁铜薄膜的光记录特性[J].光学学报,1994,14(10):1049-1051.Chen Q Y,Gu D H,He H L,et al.Optical recording properties of copper phthalocyanine film[J].Acta.Optica.Sica.,1994,10(14):1050-1053.
[11] Bradshaw J T,Mendes S B,Saavedra S S.Planar integrated optical waveguidespectroscopy[J].Anal.Chem.,2005,77(1):28A-36A.

[1]	Samuel Lascio, Hai-Feng Ji. Optical,Optoelectronic,and Photocatalytic Applications of Phosphorus Nanomaterials [J]. Imaging Science and Photochemistry, 2017, 35(5): 587-602.
[2]	ZHANG Xiang, FEI Fei, GUO Wenrui, NIE Shuhong, WU Liangzhuan, XIE Jianjun, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Fully Printed Thin-film Transistors Based on PFO-DPP Sorted Semiconducting Single-walled Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2016, 34(2): 136-143.
[3]	LIU Zhen, XU Wenya, QIAN Long, ZHAO Jianwen, CUI Zheng. Optical and Electrical Properties of Printed Thin-film Transistors Based on Poly[2,7-(9,9-dioctylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole](PFO-DBT) Sorted Semiconducting Single-walled Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2014, 32(3): 260-266.
[4]	XIA Dong-lin, LEI Pan, SHI Zheng-zhong, XU Jun. Influences of Deposition Potential on ZnS Thin Films Prepared by Electrodeposition Technique [J]. Imaging Science and Photochemistry, 2012, 30(2): 129-133.
[5]	YU Ming-guang, CHEN Guang-xue, CHEN Qi-feng, HUANG Wen-tao, QU Zhen-cai, ZHU Zhi-wei. Study on Super-Hydrophilic of TiO₂ and Erasable Printing Plates [J]. Imaging Science and Photochemistry, 2012, 30(1): 71-77.
[6]	QIAN Ling-feng, ZHANG Jia, XUE Min-zhao, ZHU Yuan-yuan, ZHANG Qing, LIU Yan-gang. Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine [J]. Imaging Science and Photochemistry, 2011, 29(2): 114-122.
[7]	XIA Dong-lin, WANG Hui-fang, SHI Zheng-zhong, ZHANG Xing-liang, LIU Jun. Preparation and Characterization of Boron-Doped p-type a-Si:H Thin Film [J]. Imaging Science and Photochemistry, 2010, 28(4): 296-304.
[8]	ZHANG Tian-bao, LI Jin-pei. Effects of UV Light Irradiation on Conductive and Transmittance Properties of AZO Films [J]. Imaging Science and Photochemistry, 2010, 28(2): 95-103.
[9]	ZHANG Tian-bao, LI Jin-pei. Effects of Preparing Conditions on Structure and Electrical Properties of AZO Films [J]. Imaging Science and Photochemistry, 2009, 27(6): 452-461.
[10]	ZHOU Lin, HU Jin-mei, GUO Si-yuan. Electrostatic Self-Assembly Multilayer Films of B-PE and Its Spectrum Characteristic [J]. Imaging Science and Photochemistry, 2009, 27(1): 57-62.
[11]	MAMUT Mariya, MAHMUT Mamtimin, MAHMUT Malikizat, ABLIZ Abdusalam, YIMIT Abliz. Fabrication of the Optical Waveguide Ethanol Gas Sensor [J]. Imaging Science and Photochemistry, 2008, 26(4): 285-290.
[12]	ZHANG Feng, TAO Jie, TAO Hai-jun, DONG Xiang. Preparation and Photoelectric Performance of Flexible Titania Nanotubes Thin Film [J]. Imaging Science and Photochemistry, 2008, 26(3): 224-232.
[13]	LUO Qian, XUE Min-zhao, ZHANG Qing, SHENG Qiao-rong, LIU Yan-gang. Research on Polymorph of Copper Phthalocyanine and Preparation of its Ultrafine Particles [J]. Imaging Science and Photochemistry, 2007, 25(4): 275-283.
[14]	WANG Chun-xiang, ZHANG Qing, XUE Min-zhao, SHENG Qiao-rong, LIU Yan-gang. Effects and Mechanism of ITO and ZnO Substrate on Surface Morgraphology and Structural of Electrodeposited Cu₂O Thin Films [J]. Imaging Science and Photochemistry, 2007, 25(1): 18-23.
[15]	WANG Wei, WANG Bo-tao, DONG Xiao-gang, XUE Yu-zhi. Preparation of the ZnO:Al Thin Films by Sol-Gel and Study on Their Preparation Technics Conditions [J]. Imaging Science and Photochemistry, 2007, 25(1): 63-68.