Imaging Science and Photochemistry ›› 1994, Vol. 12 ›› Issue (1): 45-50.DOI: 10.7517/j.issn.1674-0475.1994.01.45

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STUDY ON THE AGGREATION OF GA-SULFO PHTHALOCYANINE

WU XING, ZHANG AI-GUANG, YAO RONG, ZHANG Guo-LIN, XU ZHI-QING, PAN LAN   

  1. Department of Chemistry, yangzhou Teachers College, Yangzhou 225002, P. R. China
  • Received:1993-01-13 Revised:1993-04-26 Online:1994-02-20 Published:1994-02-20

Abstract: The aggregation of Ga-sulfopthlocyanine has been studied.Dimerization constantsare reported.The effects of pH, ionic strength,water,temperature, and sulfonation numberon the aggregation are also discussed.The experimental results show that Ga-sulfophth-alocyanine aggregative reaction can be expressed as follows: 2SPcGaOH⇔(SPcGa)2O+H2O It also shows that the greater the ionic strength,the sulfonation number,and the concentration of water the greater the dimerization constants of Ga-sulfophthalocyanine willbe.

Key words: gallium, phthalocyanine, aggregation, spectrophotometry