Imaging Science and Photochemistry ›› 2009, Vol. 27 ›› Issue (6): 401-408.DOI: 10.7517/j.issn.1674-0475.2009.06.401

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Inhibition of Photo-Induced Silver Nanoparticles to Response Current of Glucose Biosensor

MA Shi-yu1,2, QU Yi2, MU Jin1, WANG Guo-jun2, JIANG Long3   

  1. 1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China;
    2. Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China;
    3. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
  • Received:2009-03-31 Revised:2009-04-27 Online:2009-11-23 Published:2009-11-23

Abstract: The silver nanoparticle/chitosan composite matrix was developed to fabricate the glucose biosensor. The response current of the enzyme electrode containing AgNPs photo-induced at different time was characterized by chronoamperometry. The experimental results indicated that the response current of the glucose biosensor was inhibited by the photo-induced silver nanoparticles. The inhibitory effect of silver nanoparticles enhanced along with the photo-induced time. When the photo-induced time of silver nanoparticles was 120 min,the response current of the glucose biosensor reached the minimum value,-3.953 μA/cm2. The inhibition of response current of the glucose biosensor is probably due to the change of Ag+ ions concentration and the new surface formation of silver nanoparticles.

Key words: silver nanoparticle, illumination, glucose oxidase, response current, inhibition

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