水溶性Pt(II)-Salen配合物的合成、表征和光催化制氢研究

doi:10.7517/j.issn.1674-0475.2012.06.456

影像科学与光化学 ›› 2012, Vol. 30 ›› Issue (6): 456-462.DOI: 10.7517/j.issn.1674-0475.2012.06.456

水溶性Pt(II)-Salen配合物的合成、表征和光催化制氢研究

樊仁杰^1,2, 陈勇¹, 傅文甫¹

1. 中国科学院理化技术研究所,北京 100190;
2. 中国科学院研究生院,北京 100049

收稿日期:2012-05-09 修回日期:2012-06-29 出版日期:2012-11-15 发布日期:2012-11-15
通讯作者: 傅文甫

Synthesis, Characterization and Photocatalytic Hydrogen Production of Water-Soluble Pt(II)-Salen Complex

FAN Ren-jie^1,2, CHEN Yong¹, FU Wen-fu¹

1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduated University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2012-05-09 Revised:2012-06-29 Online:2012-11-15 Published:2012-11-15

摘要/Abstract

摘要： 本文合成了一种水溶性的Pt(II)-Salen配合物(Salen=双5-磺酸钾水杨醛合邻苯二胺席夫碱),将其用于光催化制氢.研究发现在光催化制氢体系中仅存在Pt(II)-Salen配合物和三乙胺(TEA)而没有额外加入催化剂时,在可见光照射下有氢气产生.进一步的研究表明,Pt(II)-Salen配合物在体系中既是光敏剂,又是催化剂Pt纳米粒子的前体.同时,制氢体系中除了TEA外没有使用有机溶剂.该结果为简化多组分制氢体系提供了新思路.

关键词: 水溶性, 铂配合物, Salen配体, 光催化制氢

Abstract: A new water-soluble Pt(II) -Salen complex (Salen=NN'-substituted bis(salicyl-aldimine-5-sulphonic acid) potassium salt) was synthesized, characterized and employed in the photocatalytic hydrogen evolution system. In the presence of TEA, this system could produce hydrogen effectively without additional catalyst. An investigation found that the Pt(II) -Salen complex could be employed as photosensitizer. Besides, it could also be the precursor of the catalyst. In addition, there was not organic solvent except TEA in the hydrogen evolution system. The result provided a new way to simplify the multi-component system for photocatalytic hydrogen production.

Key words: water-soluble, platinum(II) complex, Salen, photocatalytic hydrogen production

中图分类号:

樊仁杰, 陈勇, 傅文甫. 水溶性Pt(II)-Salen配合物的合成、表征和光催化制氢研究[J]. 影像科学与光化学, 2012, 30(6): 456-462.

FAN Ren-jie, CHEN Yong, FU Wen-fu. Synthesis, Characterization and Photocatalytic Hydrogen Production of Water-Soluble Pt(II)-Salen Complex[J]. Imaging Science and Photochemistry, 2012, 30(6): 456-462.

参考文献

[1] Hoffert M I, Caldeira K, Jain A K, Haites E F, Harvey L D D, Potter S D, Schlesinger M E, Schneider S H, Watts R G, Wigley T M L, Wuebbles D J. Energy implications of future stabilization of atmospheric CO₂ content[J]. Nature,1998, 395(6705): 881-884.
[2] Lewis N S, Nocera D G. Powering the planet: chemical challenges in solar energy utilization[J]. Proc. Natl. Acad. Sci.USA, 2006, 103(43): 15729-35.
[3] World Energy Assessment Report: Energy and the Challenge of Sustainability[M]. Program, U. N. D., Ed. United Nations: New York, 2003.
[4] Petit J R, Jouzel J, Raynaud D, Barkov N I, Barnola J M, Basile I, Bender M, Chappellaz J, Davis M, Delaygue G, Delmotte M, Kotlyakov V M, Legrand M, Lipenkov V Y, Lorius C, Pepin L, Ritz C, Saltzman E, Stievenard M. Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica[J]. Nature, 1999, 399(6735): 429-436.
[5] Siegenthaler U, Stocker T F, Monnin E, L thi D, Schwander J, Stauffer B, Raynaud D, Barnola J-M, Fischer H, Masson-Delmotte V, Jouzel J. Stable carbon cycle climate relationship during the late pleistocene[J]. Science, 2005, 310(5752): 1313-1317.
[6] Esswein A J, Nocera D G. Hydrogen production by molecular photocatalysis[J]. Chem. Rev., 2007, 107(10): 4022-4047.
[7] 何礼青, 骆超, 周前雄, 侯原军, 张宝文, 王雪松. 利用静电吸引作用提高光催化放氢效率[J]. 影像科学与光化学, 2011, 29(4): 270-277. He L Q, Luo C, Zhou Q X, Hou Y J, Zhang B W, Wang X S. Use electrostatic attraction to improve the photocatalytic hydrogen evolution efficiency[J]. Imaging Science and Photochemistry, 2011, 29(4): 270-277.
[8] Berry K J, Moya F, Murray K S, van den Bergen A M B, West B O. Water-soluble cobalt(II) complexes of NN'-substituted bis(salicylaldimine-5-sulphonic acids). Oxygen-carrying properties and conversion into cobalt(III) organometallic compounds[J]. J. Chem. Soc., Dalton Trans., 1982, (1): 109-116.
[9] Botsivali M, Evans D F, Missen P H, Upton M W. Studies on singlet oxygen in aqueous solution. Part 2. Water-soluble square-planar nickel complexes as quenchers[J]. J. Chem. Soc., Dalton Trans., 1985,(6): 1147-1149.
[10] Che C-M, Kwok C-C, Lai S-W, Rausch A F, Finkenzeller W J, Zhu N, Yersin H. Photophysical properties and OLED applications of phosphorescent platinum(II) schiff base complexes[J]. Chem. Eur. J., 2010, 16(1): 233-247.
[11] Du P, Schneider J, Jarosz P, Eisenberg R. Photocatalytic generation of hydrogen from water using a platinum(II) terpyridyl acetylide chromophore[J]. J. Am. Chem. Soc., 2006, 128(24): 7726-7727.
[12] Teets T S, Nocera D G. Photocatalytic hydrogen production[J]. Chem. Commun., 2011, 47(33): 9268-9274.
[13] Du P, Schneider J, Li F, Zhao W, Patel U, Castellano F N, Eisenberg R. Bi- and terpyridyl platinum(II) chloro complexes: molecular catalysts for the photogeneration of hydrogen from water or simply precursors for colloidal platinum[J]. J. Am. Chem. Soc., 2008, 130(15): 5056-5058.
[14] Lei P, Hedlund M, Lomoth R, Rensmo H, Johansson O, Hammarstrm L. The role of colloid formation in the photoinduced H₂ production with a Ru^II-Pd^II supramolecular complex: a study by GC, XPS, and TEM[J]. J. Am. Chem. Soc., 2007, 130(1): 26-27.

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水溶性Pt(II)-Salen配合物的合成、表征和光催化制氢研究

Synthesis, Characterization and Photocatalytic Hydrogen Production of Water-Soluble Pt(II)-Salen Complex

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