新型的含葡萄糖胺的水溶性高分子型硫杂蒽酮光引发剂

doi:10.7517/j.issn.1674-0475.2007.06.445

影像科学与光化学 ›› 2007, Vol. 25 ›› Issue (6): 445-451.DOI: 10.7517/j.issn.1674-0475.2007.06.445

新型的含葡萄糖胺的水溶性高分子型硫杂蒽酮光引发剂

李浩, 姜学松, 印杰

上海交通大学, 化学化工学院, 高分子材料研究所, 上海, 200240

收稿日期:2007-01-24 修回日期:2007-06-13 出版日期:2007-11-23 发布日期:2007-11-23
通讯作者: 姜学松,E-mail:ponygle@sjtu.edu.cn.
基金资助:
上海市科委重点项目(06JC14041)

A Novel Water-Soluble Polymeric Thioxanthone Photoinitiator Containing Glucamine

LI Hao, JIANG Xue-song, YIN Jie

Research Institute of Polymer Materials, School of Chemistry & Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2007-01-24 Revised:2007-06-13 Online:2007-11-23 Published:2007-11-23

摘要/Abstract

摘要： 将硫杂蒽酮光引发剂(TX)和共引发剂葡萄糖胺(GA)引入同一个高分子链上,合成新型水溶性高分子型硫杂蒽酮光引发剂(PTX-GA).通过改变PTX-GA中TX与GA的比例,合成了PTX-GA1、PTX-GA2、PTX-GA3,并通过光膨胀计实验研究了3种引发剂引发丙烯酰胺聚合的能力.研究表明这种水溶性高分子型硫杂蒽酮光引发剂即使在没有共引发剂胺的情况下,引发丙烯酰胺(AAM)的聚合效率也非常显著.同时由于它具有水溶性,而且含有生物分子,有利于改善光引发剂的生物相容性.

关键词: 水溶性, 高分子型光引发剂, 硫杂蒽酮, 葡萄糖胺

Abstract: A novel type of water-soluble polymeric thioxanthone photoinitiator containing glucamine (PTX-GA) was synthesized by introducing thioxanthone (TX) moieties and glucamine (GA) group into the same polyacylate chain.Through changing the proportion of thioxanthone and coinitiator amine,three kinds of macrophotoinitiators were synthesized.Photopolymerizations of acrylamide (AAM) initiated by these macrophotoinitiators were studied through photo-dilatometer.The result show that this kind of water-soluble polymeric photoinitiator can initiate polymerization acrylamide (AAM) effectively in absence of coinitiator amine,and might be used in biomaterials such as dental materials.

Key words: water-soluble, polymeric photoinitiator, thioxanthone, glucamine

中图分类号:

李浩, 姜学松, 印杰. 新型的含葡萄糖胺的水溶性高分子型硫杂蒽酮光引发剂[J]. 影像科学与光化学, 2007, 25(6): 445-451.

LI Hao, JIANG Xue-song, YIN Jie. A Novel Water-Soluble Polymeric Thioxanthone Photoinitiator Containing Glucamine[J]. Imaging Science and Photochemistry, 2007, 25(6): 445-451.

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新型的含葡萄糖胺的水溶性高分子型硫杂蒽酮光引发剂

A Novel Water-Soluble Polymeric Thioxanthone Photoinitiator Containing Glucamine

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