STUDY ON EFFECTS OF SOLVENTS ON THE OPTICAL PROPERTIES OF CYANINE DYE FILM WITH AFM

doi:10.7517/j.issn.1674-0475.2001.04.257

Abstract

Abstract: In CD R optical disc,the recording media film should have nice optical properties in order to depress reading noise and increase the reliability when data are processed.Cyanine dyes are one of the most popular recording media.When the cyanine dye was spin coated in this experiment,it was found that the solvents had great influence on the dye film.The observation on the film surface with AFM indicated that the reflectance was closely related to the roughness of film.Dye films were flat and had high reflectance when cholroform,tetrafluoro propanol or diacetone alcohol were used as the solvent,respectively.When the solvent was methanol,many mirco crystals sized 0.3 μm were found in the dye film,which had great scattering effect on the light and resulted in the decrease of the light reflectance.

Key words: cyanine dye film, solvent effect, AFM

CLC Number:

TQ57

ZHOU Shu-yun, ZHANG Jun-ping, CHEN Ping, OKASAKI Tsuneki, HAYAMI Masaaki. STUDY ON EFFECTS OF SOLVENTS ON THE OPTICAL PROPERTIES OF CYANINE DYE FILM WITH AFM[J]. Imaging Science and Photochemistry, 2001, 19(4): 257-261.

References

[1] 干福熹.数字光盘和光存储材料[M].上海:上海科学技术出版社,1992.Gan F X. Digital Optical Disc and Photo-Storage Materials[M]. Shanghai: Shanghai Science and Technology Perss,1992.
[2] 杨松杰,田禾.菁染料光稳定性研究进展[J].感光科学与光化学,1999,17(3):275-283.Yang S J,Tian H. Advance in photo-stability of cyanine dyes[J]. Photographic Science and Photochemistry, 1999,17(3):275-283.
[3] 孙树清,陈萍.可录型光盘与菁染料光存储媒体的研究进展[J].化学通报,1999,(6):20-24.Sun S Q,Chen P. Advance in recordable optical disc and cyanine dyes applied as photo-storge media[J]. Hua Xue Tong Bao, 1999, (6): 20-24.
[4] 李军,陈萍,郑德水.有机光存储材料及其进展[J].功能材料,1996,27(1):1-5.Li J, Chen P, Zheng D S. Organic photo storage materials and their advancement[J]. Functional Materials, 1996,27(1):1-5.
[5] Jong S K,Tae Y N, Young J H. The optical characteristics in the layer of compact disc-recordable[J]. Korean J. of Chem. Eng., 1997,14(2):88-92.
[6] Chen P, Zhao J, Zheng D S, Thermodynamic property and recording mechanism of indolenine cyanine dye for optical memory medium[J]. J. Information Recording, 1997 24(2):585-592.
[7] 孙树清,陈萍,郑德水,等.可录型光盘(CD-R)中染料膜层的光谱性质和光学性质[J].感光科学与光化学,1999,17(2):134-140.Sun S Q, Chen P, Zheng D S, et al. Spectroscopic and optical properties of dye film in compact disc recordable[J].Photographic Science and Photochemistry, 1999,17(2): 134-140.
[8] Sun S Q, Chen P, Zhou S Y, et al. Optical and thermal properties of cyanine dye medium for next generation DVD-Rs[J]. The Imaging Science Journal, 1999,47(3): 113-116.
[9] 顾冬红,陈启婴,唐晓东,等.光记录有机薄膜的扫描隧道显微镜研究[J].中国激光,1995,A22(7):551-555.Gu D H, Chen Q Y, Tang X D, et al. Study on optical storage organic thin film with STM[J]. China Laser, 1995, A22(7):551-555.

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